Co(II)((1,2-cyclohexanedione dioximate(2-))3(B(C4H2SC4H3S))2) | 1242328-63-7

• 英文名称: Co(II)((1,2-cyclohexanedione dioximate(2-))3(B(C4H2SC4H3S))2)
• 英文别名: Co((nioximate(2-))3(B(C4H2SC4H3S))2)
• CAS: 1242328-63-7
• 化学式: C₃₄H₃₄B₂CoN₆O₆S₄
• 分子量: 831.56
• InChiKey: YYUQMVXKSIPFQP-YGIJSTTDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Co(II)((1,2-cyclohexanedione dioximate(2-))3(B(C4H2SC4H3S))2) 在 (C₄H₉)4NPF₆ 、 Pt 作用下， 以 二氯甲烷 为溶剂， 生成 [Co((nioximate(2-))3(B(C4H2SC4H2S))2)]n
  参考文献：
  名称：

  Layer-by-Layer Synthesis of Metal-Containing Conducting Polymers: Caged Metal Centers for Interlayer Charge Transport

  摘要：

  Metal-templated [2 + 3]-type cocondensation of a pi-extended boronic acid and nioxime furnished a series of cage molecules, which were electropolymerized to prepare metal-containing conducting polymers (MCPs). Despite sharing essentially isostructural organic scaffolds, these materials display metal-dependent electrochemical properties as evidenced by different redox windows observed for M = Co, Fe, Ru. Consecutive electropolymerization using two different monomers furnished bilayer MCPs having different metals in each layer. In addition to functioning as heavy atom markers in cross-sectional analysis by FIB and EDX, redox-active metal centers participate in voltage-dependent interlayer electron transport to give rise to cyclic voltammograms that are distinctively different from those of each layer alone or random copolymers. A simple electrochemical technique can thus be used as a straightforward diagnostic tool to investigate the structural ordering of electrically conductive layered materials.

  DOI：

  10.1021/ja104038s
• 作为产物：
  描述：

  钴 、 1,2-环已二酮二肟 、 2,2’-联噻吩-5-硼酸 以 甲醇 为溶剂， 生成 Co(II)((1,2-cyclohexanedione dioximate(2-))3(B(C4H2SC4H3S))2)
  参考文献：
  名称：

  Layer-by-Layer Synthesis of Metal-Containing Conducting Polymers: Caged Metal Centers for Interlayer Charge Transport

  摘要：

  Metal-templated [2 + 3]-type cocondensation of a pi-extended boronic acid and nioxime furnished a series of cage molecules, which were electropolymerized to prepare metal-containing conducting polymers (MCPs). Despite sharing essentially isostructural organic scaffolds, these materials display metal-dependent electrochemical properties as evidenced by different redox windows observed for M = Co, Fe, Ru. Consecutive electropolymerization using two different monomers furnished bilayer MCPs having different metals in each layer. In addition to functioning as heavy atom markers in cross-sectional analysis by FIB and EDX, redox-active metal centers participate in voltage-dependent interlayer electron transport to give rise to cyclic voltammograms that are distinctively different from those of each layer alone or random copolymers. A simple electrochemical technique can thus be used as a straightforward diagnostic tool to investigate the structural ordering of electrically conductive layered materials.

  DOI：

  10.1021/ja104038s