(μ-oxo)hexakis(N,N-diethyldithiocarbamato)dimolybdenum(IV,V) tetrafluoroborate | 88253-60-5

• 英文名称: (μ-oxo)hexakis(N,N-diethyldithiocarbamato)dimolybdenum(IV,V) tetrafluoroborate
• CAS: 88253-60-5
• 化学式: BF₄*C₃₀H₆₀Mo₂N₆OS₁₂
• 分子量: 1184.32
• InChiKey: AYXDNCMEQXTBBV-UHFFFAOYSA-H

反应信息

• 作为产物：
  描述：

  {MoO(S2CNEt2)3}BF4 在 triphenylphosphine 作用下， 以 甲醇 为溶剂， 以65%的产率得到(μ-oxo)hexakis(N,N-diethyldithiocarbamato)dimolybdenum(IV,V) tetrafluoroborate
  参考文献：
  名称：

  Broomhead, John A.; Sterns, Meta; Young, Charles G., Inorganic Chemistry, 1984, vol. 23, # 6, p. 729 - 737

  摘要：

  DOI：

文献信息

• Synthesis and X-ray structural characterization of [Mo₂O(S₂CNEt₂)₆]BF₄,a µ-oxo-bridged mixed oxidation state complex of molybdenum
  作者：John A. Broomhead、Meta Sterns、Charles G. Young

  DOI：10.1039/c39810001262

  日期：——

  The reaction of [MoO(S2CNEt2)3]BF4 and PPh3 in methanol under anaerobic conditions results in the formation of [Mo2O(S2CNEt2)6]BF4, an X-ray crystal structur of which shows a new type of µ-oxo-bridging between two molybdenum atoms each having a formal oxidation state of 4·5.