trans-bis(isothiocyanato)(methoxy)(phenylimido)bis(triphenylphosphine)rhenium(V) | 166041-17-4

• 英文名称: trans-bis(isothiocyanato)(methoxy)(phenylimido)bis(triphenylphosphine)rhenium(V)
• CAS: 166041-17-4
• 化学式: C₄₅H₃₈N₃OP₂ReS₂
• 分子量: 949.103
• InChiKey: AXKMHQYMXWEGOJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  trichloro(phenylimido)bis(triphenylphosphine)rhenium(V) 、 potassium thioacyanate 生成 trans-bis(isothiocyanato)(methoxy)(phenylimido)bis(triphenylphosphine)rhenium(V)
  参考文献：
  名称：

  Isothiocyanato Complexes of Rhenium. V. trans-Bis(isothiocyanato)(methoxy)(phenylimido)bis(triphenylphosphine)rhenium(V)

  摘要：

  The title compound consists of well separated molecules of [Re(C6H5N)(CH3O)(NCS)(2)(C18H15P)(2)]. The Re atom is six-coordinate in a distorted octahedral environment. The two triphenylphosphine ligands are arranged trans to each other and there is a methoxy group in the position trans to the phenylimido group. The Re-NPh distance is 1.744(4) Angstrom and the NCS ligands are coordinated via the N atom.

  DOI：

  10.1107/s0108270195000564