cis-[Re(CO)4(P(OMe)3)Cl] | 134770-96-0

• 英文名称: cis-[Re(CO)4(P(OMe)3)Cl]
• 英文别名: cis-Re(CO)4(P(OMe)4)Cl
• CAS: 134770-96-0
• 化学式: C₇H₉ClO₇PRe
• 分子量: 457.778
• InChiKey: ZODBTENEVOGOBE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  cis-[Re(CO)4(P(OMe)3)Cl] 、 1,4-双(吡啶-4-基乙炔基)苯 以 苯 为溶剂， 以33%的产率得到[fac-Re(CO)3(P(OMe)3)Cl]2(μ-4,4'-dipyridylbutadiyne)
  参考文献：
  名称：

  Rhenium carbonyls containing pyridyl ligands incorporating an alkyne entity

  摘要：

  Reactions of pyridyl ligands, 4,4'-dipyridylbutadiyne (DPB), 1,4-bis(4'-pyridylethynyl)benzene (BPEB), ferrocenyl-4-pyridylacetylene (FPA), 4-nitrophenyl-4'-pyridylacetylene (NPPA) and 4-aminophenyl-4'-pyridylacetylene (APPA), with Re(CO)(5)X (X = Cl,Br), cis-Re(CO)(4)(L)Cl (L = PPh(3), P(OMe)(3)), and [Re(CO)(3)(2,2'-bipy)(MeCN)][PF6], provides fac-Re(CO)(3)(eta(1)-DPB)(2)Cl (1), fac-Re(CO)(3)(PY)(2)Br (2, PY = FPA; 3, L = NPPA; 4, L = APPA), [fac-Re(CO)(3)(PPh(3))Cl](2)(mu-PY) (5, PY = BPEB; 6, PY = DPB), [fac-Re(CO)(3)(P(OMe)(3))Cl](2)(mu-DPB) (7), fac-Re(CO)(3)(PPh(3))(PY)Cl (8, PY = NPPA; 9, PY = FPA), [fac-Re(CO)(3)(2,2'-bipy)(PY)][PF6] (10, PY = NPPA; 11, PY = APPA; 12, PY = FPA), and [(fac-Re(CO)(3)(2,2'-bipy)}(2)(mu-PY)][PF6](2) (13, PY = DPB; 14, PY = BPEB). The energy of the metal to pyridyl pi* charge-transfer (MLCT) is investigated by electronic absorption spectra and cyclic voltammetry, X-ray structural analyses for 2 . CH2Cl2 and 12 . 2H(2)O were carried out. 2 . CH2Cl2:C12H28BrClN2O3P2Fe2Re; monoclinic; P2(1)/n, Z = 4; a = 15.188(2), b = 15.100(2), c = 16.254(1) Angstrom; beta = 102.22(1)degrees; R = 0.047; Rw = 0.040. 12 . 2H(2)O: C30H21F6N3O3PFeRe; monoclinic; P2(1)/n, Z = 4; a = 19.022(4), b = 9.339(2), c = 21.111(3) Angstrom; beta = 116.156(9)degrees; R = 0.043; Rw = 0.061.

  DOI：

  10.1016/0022-328x(96)06167-0
• 作为产物：
  描述：

  在 氯仿 作用下， 以 正己烷 为溶剂， 生成 cis-[Re(CO)4(P(OMe)3)Cl]
  参考文献：
  名称：

  Hanckel, John M.; Lee, Kang-Wook; Rushman, Paul, Inorganic Chemistry, 1986, vol. 25, # 11, p. 1852 - 1856

  摘要：

  DOI：

文献信息

• The PdO catalysed reaction between Re(CO)5X (X  Cl, Br, I) and L (L  Group 15 donor ligand). Synthesis of Re(CO)4LX
  作者：Ann E. Leins、Neil J. Coville

  DOI：10.1016/0022-328x(91)86314-g

  日期：1991.4

  Previously there has been no high yielding synthesis of Re(CO)4LX (L = Group 15 donor ligand, X = Cl, Br, I). We here show that the PdO-catalysed reaction between Re(CO)5X and L gives Re(CO)4LX in > 75% yield when L has a cone angle less than 150-degrees. The new complexes have been fully characterised by IR and H-1 NMR spectrscopy.