[PdCl2(triphenylphosphine)(thiourea)]*methanol | 919785-87-8

• 英文名称: [PdCl2(triphenylphosphine)(thiourea)]*methanol
• 英文别名: [PdCl2(PPh3)(tu)]*CH3OH
• CAS: 919785-87-8
• 化学式: CH₄O*C₁₉H₁₉Cl₂N₂PPdS
• 分子量: 547.781
• InChiKey: GAASDSBYAJMKOV-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  甲醇 、 双(乙腈)氯化钯(II) 、 硫脲 、 三苯基膦 以 甲醇 、 氯仿 为溶剂， 以45%的产率得到[PdCl2(triphenylphosphine)(thiourea)]*methanol
  参考文献：
  名称：

  Supramolecular assemblies of cis-palladium complexes dominated by CH⋯Cl interactions

  摘要：

  Two cis-related palladium(II) complexes [PdCl(2)(PPh(3))(tu)] (1) and [PdCl(2)(tmen)] (2) {PPh(3) = triphenylphosphine, tu = thiourea, tmen = N,N,N,N-tetramethylethylenediamine} have been synthesized and characterized by elemental analysis, IR and NMR spectroscopies, and single crystal X-ray diffraction. In 1, N-H center dot center dot center dot Cl hydrogen bonds are responsible for the formation of a dimer which connects to an adjacent one through weak C-H center dot center dot center dot Cl interactions, yielding 1D tapes. The crystal packing of compound 2 consists of zigzag ribbons of [PdCl(2)(tmen)] self-assembled by C-H center dot center dot center dot Cl hydrogen bonds which also holds the chains together, giving rise to a 2D layered structure. (C) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2006.02.012