| 1312012-41-1

• CAS: 1312012-41-1
• 化学式: C₃₄H₂₄Cl₂N₂O₂P₂Pt
• 分子量: 820.51
• InChiKey: IDMDANRBODQWQS-AXCIXSNOSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  potassium tetrachloroplatinate(II) 、 9-Phenylphosphindolo[2,3-c]pyridine 9-oxide 以 乙醇 、 水 为溶剂， 以62%的产率得到
  参考文献：
  名称：

  Azadibenzophospholes: Functional Building Blocks with Pronounced Electron-Acceptor Character

  摘要：

  A series of azadibenzophospholes with varying location of the nitrogen center has been synthesized and comprehensively characterized. In the context of the study, suitably brominated phenylpyridine precursors were accessed via Suzuki-Miyaura cross-coupling for the first time. Despite being nonfluorescent, X-ray crystallographic studies of two azadibenzophosphole oxides revealed planar conjugated scaffolds with high degree of pi-conjugation. The P-oxidized species were found to show desirable reversible reduction features that support promising electron-accepting properties of the materials. The presence of the nitrogen as well as phosphorus centers within the scaffold allowed for further functionalization with transition metals, as well as methyl groups that result in altered absorption and redox features for the materials. Subsequent bromination of the scaffold selectively occurred at the exocydic P-phenyl group, as confirmed via X-ray crystallography. This halogenation allowed for further modification of the system via catalytic cross-coupling with pyridine.

  DOI：

  10.1021/ic200951x