dicarbonyl(methoxycarbonylvinylidene)bis(triethylphosphane)iron | 198569-50-5

• 英文名称: dicarbonyl(methoxycarbonylvinylidene)bis(triethylphosphane)iron
• CAS: 198569-50-5
• 化学式: C₁₈H₃₄FeO₄P₂
• 分子量: 432.26
• InChiKey: ITAXSFVBYOEKNA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  dicarbonyl(methoxycarbonylvinylidene)bis(triethylphosphane)iron 、 丙炔酸甲酯 以 乙醚 为溶剂， 以9%的产率得到carbonyl[2,4,6-tris(methoxycarbonyl)-hexa-1,3,5-trien-1,5-diyl]bis(triethylphosphane)iron
  参考文献：
  名称：

  Methyl propiolate coupling at the Fe(CO)2(PEt3)2 fragment

  摘要：

  The in situ solution mixture of Fe(CO)(2)(PEt3)(2)(N-2) 3a and (mu-N-2)[Fe(CO)(2)(PEt3)(2)](2) 3b reacts with HC=CCOOMe to afford an acetylene Fe(CO)(2)(PEt3)(2)(eta(2)-HC=CCOOMe) 4a and an acetylido hydride complex Fe(CO)(2)(PEt3)(2)(H)(C=CCOOMe) 4b as primary products. Compounds 4a and 4b are in equilibrium. The equilibrium mixture is irreversibly converted to a vinylidene species Fe(CO)(2)(PEt3)(2)(C=CHCOOMe) 5 in the presence of silylated silica. Addition of further equivalents of HC=CCOOMe to 5 leads to the isolation of carbonyl[2,4,6-tris(methyoxycarbonyl)-hexa-1,3,5-trien-1,5-diyl]bis(triethylphosphane)iron 9 and dicarbonyl[methoxycarbonyl(1,4-di-methoxycarbonyl-buta-1,3-dien-2-y)vinylidene]bis(triethylphosphane)iron 10 as iron-bound trimerization products of HC=CCOOMe. 10 was characterized by a single crystal X-ray diffraction study. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00132-0
• 作为产物：
  描述：

  dicarbonyl(methylpropyonate)bis(triethylphosphane)iron 、 dicarbonylhydrido(methylpropyonate-1-yl)bis(triethylphosphane)iron 在 SiO₂ 作用下， 以 正己烷 为溶剂， 以58%的产率得到dicarbonyl(methoxycarbonylvinylidene)bis(triethylphosphane)iron
  参考文献：
  名称：

  Methyl propiolate coupling at the Fe(CO)2(PEt3)2 fragment

  摘要：

  The in situ solution mixture of Fe(CO)(2)(PEt3)(2)(N-2) 3a and (mu-N-2)[Fe(CO)(2)(PEt3)(2)](2) 3b reacts with HC=CCOOMe to afford an acetylene Fe(CO)(2)(PEt3)(2)(eta(2)-HC=CCOOMe) 4a and an acetylido hydride complex Fe(CO)(2)(PEt3)(2)(H)(C=CCOOMe) 4b as primary products. Compounds 4a and 4b are in equilibrium. The equilibrium mixture is irreversibly converted to a vinylidene species Fe(CO)(2)(PEt3)(2)(C=CHCOOMe) 5 in the presence of silylated silica. Addition of further equivalents of HC=CCOOMe to 5 leads to the isolation of carbonyl[2,4,6-tris(methyoxycarbonyl)-hexa-1,3,5-trien-1,5-diyl]bis(triethylphosphane)iron 9 and dicarbonyl[methoxycarbonyl(1,4-di-methoxycarbonyl-buta-1,3-dien-2-y)vinylidene]bis(triethylphosphane)iron 10 as iron-bound trimerization products of HC=CCOOMe. 10 was characterized by a single crystal X-ray diffraction study. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00132-0