dichloro[2-(3,4-dichlorophenyl)imino-κN-N-(2-thiazolin-κN-2-yl)thiazolidine]cobalt(II) | 844841-57-2

• 英文名称: dichloro[2-(3,4-dichlorophenyl)imino-κN-N-(2-thiazolin-κN-2-yl)thiazolidine]cobalt(II)
• 英文别名: [CoCl2(2-(3,4-dichlorophenyl)imino-N-(2-thiazolin-2-yl)thiazolidine)]
• CAS: 844841-57-2
• 化学式: C₁₂H₁₁Cl₄CoN₃S₂
• 分子量: 462.177
• InChiKey: LZPSROVKIMEOAG-HVNBYZNQSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cobalt(II) chloride hexahydrate 、 2-(3,4-dichlorophenylimino)-3-(4,5-dihydrothiazol-2-yl)thiazolidine 以 乙醇 为溶剂， 以89.2%的产率得到dichloro[2-(3,4-dichlorophenyl)imino-κN-N-(2-thiazolin-κN-2-yl)thiazolidine]cobalt(II)
  参考文献：
  名称：

  Pseudotetrahedral cobalt(II) complexes with thiazoline and thiazine derivative ligands: synthesis and characterization

  摘要：

  The cobalt(II) complexes dichloro[2-(3,4-dichlorophenyl)imino-kappaN-N-(2-thiazolin-kappaN-2-yl)thiazohdine]cobalt(II) (1) and dichloro[2-(3,4-dichlorophenyl)imino-kappaN-N-(2-thiazin-kappaN-2-yl)thiazolidine]cobalt(II) (2) have been isolated and characterized in the solid state by X-ray diffraction, elemental analysis, IR spectra, magnetic measurements and UV-Vis-NIR diffuse. reflectance spectroscopy. In both complexes, the environment around the cobalt(II) ion may be described as a distorted tetrahedral geometry, with the metallic atom coordinated to two chlorine atoms [Co-Cl(1) = 2.213(1) Angstrom; Co-Cl(2) = 2.226(1) Angstrom], one imino nitrogen [Co-N(3) = 1.992(2) Angstrom] and one thiazoline nitrogen [Co-N(1) = 1.974(2) Angstrom] in complex 1 and to two chlorine atoms [Co-Cl(1) = 2.244(2) Angstrom; Co-Cl(2) = 2.226(1) Angstrom], one imino nitrogen [Co-N(3) = 1.970(4) Angstrom] and one thiazine nitrogen [Co-N(1) = 1.946(4) Angstrom] in complex 2. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.10.011