([2-hydroxy-N'-[5-oxo-1,10-phenanthroline-6(5H)-ylidene]benzoylhydrazide])bromotricarbonylrhenium(I) | 1256931-90-4

• 英文名称: ([2-hydroxy-N'-[5-oxo-1,10-phenanthroline-6(5H)-ylidene]benzoylhydrazide])bromotricarbonylrhenium(I)
• CAS: 1256931-90-4
• 化学式: C₂₂H₁₂BrN₄O₆Re
• 分子量: 694.471
• InChiKey: CJWKFWNLCAJLFF-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  fac-bis(acetonitrile)bromotricarbonylrhenium(I) 、 2-hydroxy-N'-[5-oxo-1,10-phenanthroline-6(5H)-ylidene]benzohydrazide 以 氯仿 为溶剂， 以88.8%的产率得到([2-hydroxy-N'-[5-oxo-1,10-phenanthroline-6(5H)-ylidene]benzoylhydrazide])bromotricarbonylrhenium(I)
  参考文献：
  名称：

  Tricarbonyl Rhenium(I) and Technetium(I) Complexes with Hydrazones Derived from 4,5‐Diazafluoren‐9‐one and 1,10‐Phenanthroline‐5,6‐dione

  摘要：

  AbstractTricarbonylrhenium(I) and ‐technetium(I) halide (halide = Cl and Br) complexes of ligands derived from 4,5‐diazafluoren‐9‐one (df) and 1,10‐phenanthroline‐5,6‐dione (phen) derivatives of benzoic and 2‐hydroxybenzoic acid hydrazides have been prepared. The complexes have been characterized by elemental analysis, MS, IR, 1H NMR and absorption and emission UV/Vis spectroscopic methods. The metal centres (ReI and TcI) are coordinated through the nitrogen imine atoms and establish five‐membered chelate rings, whereas the hydrazone groups stand uncoordinated. The 1H NMR spectra suggest the same behaviour in solution on the basis of only marginal variations in the chemical shifts of the hydrazine protons.

  DOI：

  10.1002/ejic.201000522