[(4-methoxybenzoylmethylenetriphenylphosphorane)HgCl2]2 | 947753-26-6

• 英文名称: [(4-methoxybenzoylmethylenetriphenylphosphorane)HgCl2]2
• CAS: 947753-26-6
• 化学式: C₅₄H₄₆Cl₄Hg₂O₄P₂
• 分子量: 1363.9
• InChiKey: ORBKBBJJDBTTCT-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (4-methoxyphenacylidene)triphenyl phosphorane 、 mercury dichloride 以 甲醇 为溶剂， 以92%的产率得到[(4-methoxybenzoylmethylenetriphenylphosphorane)HgCl2]2
  参考文献：
  名称：

  Synthesis, spectroscopic and X-ray structural studies of mercury(II) halide complexes of 4-methoxybenzoylmethylenetriphenylphosphorane

  摘要：

  The reactions of the title ylide {(C6H5)(3)PCHCOC6H4OCH3)} (MBPPY) with mercury(II) chloride and mercury(II) bromide in equimolar ratios using methanol as the solvent produces crystals of [(MBPPY) (.) HgBr2](2) (1) and [(MBPPY) (.) HgBr2](2) (2), respectively. Single crystal X-ray analyses reveal the presence of centrosymmetric dimeric structures containing the ylide and HgX2 (X = Cl or Br) in both cases. The IR and NMR data of the product [(MBPPY) (.) HgI2](2) (3), formed by the reaction of mercury(II) iodide with the same ylide, are similar to those of 1 and 2. Analytical data indicate a 1:1 stoichiometry between the ylide and Hg(ll) halide in each of the three products. (C) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.01.053