trans-bis(ethane-1,2-dithiolato{2-}-S,S')bis(3-aminopyrazole)tin(IV) | 149999-86-0

• 英文名称: trans-bis(ethane-1,2-dithiolato{2-}-S,S')bis(3-aminopyrazole)tin(IV)
• CAS: 149999-86-0
• 化学式: C₁₀H₁₈N₆S₄Sn
• 分子量: 469.267
• InChiKey: FZARQALHAKCMGV-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  3-氨基吡唑 、 bis(ethane-1,2-dithiolato)tin 以 二氯甲烷 为溶剂， 以95%的产率得到trans-bis(ethane-1,2-dithiolato{2-}-S,S')bis(3-aminopyrazole)tin(IV)
  参考文献：
  名称：

  The structure of trans-bis(ethane-1,2- dithiolato[2−]-S,S′)bis(3-aminopyrazole)tin(IV)

  摘要：

  The 1:2 adduct of bis(ethane-1,2-dithiolato)tin(IV) with 3-aminopyrazole, [Sn(C2H4S2)2(C3H5N3)2], Crystallizes in the monoclinic C2/c space group, with Z=4, a=13.122(2), b = 11.216(2), c = 11.810(2) angstrom and beta = 98.47(2)-degrees. The structure determination, based on 2127 independent reflections, has been refined to R = 2.42%. The molecules are discrete, monomeric, trans-octahedral units, with the tin atom at the centre of symmetry, planar aminopyrazole groups and SnS2C2 groups in twist-envelope form. The aminopyrazole ligands act as monodentate and are bonded through the N(2) atoms. No significant intermolecular contacts and S...H-N hydrogen bonds are observed.

  DOI：

  10.1016/s0020-1693(00)85148-8