[(HgBr2)2(μ-R-1,1'-C20H12-2,2'-[NHC(=O)-3-C5H4N]2)(μ-S-1,1'-C20H12-2,2'-[NHC(=O)-3-C5H4N]2)] | 852548-09-5

• 英文名称: [(HgBr2)2(μ-R-1,1'-C20H12-2,2'-[NHC(=O)-3-C5H4N]2)(μ-S-1,1'-C20H12-2,2'-[NHC(=O)-3-C5H4N]2)]
• CAS: 852548-09-5
• 化学式: C₆₄H₄₄Br₄Hg₂N₈O₄
• 分子量: 1709.9
• InChiKey: DFJHQMMOPBVHLE-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (S)-2,2'-bis(3-pyridylcarbonylamino)-1,1'-binaphthyl 、 mercury dibromide 以 二氯甲烷 为溶剂， 以73%的产率得到[(HgBr2)2(μ-R-1,1'-C20H12-2,2'-[NHC(=O)-3-C5H4N]2)(μ-S-1,1'-C20H12-2,2'-[NHC(=O)-3-C5H4N]2)]
  参考文献：
  名称：

  Self-Assembly of Chiral Coordination Polymers and Macrocycles:  A Metal Template Effect on the Polymer−Macrocycle Equilibrium

  摘要：

  The self-assembly of racemic and enantiopure binaphthyl-bis(amidopyridyl) ligands 1,1'-C20H12{NHC(=O)-4-C5H4N}(2), 1, and 1,1'-C20H12{NHC(=O)-3-C5H4N}(2), 2, with mercury(II) halides (HgX2; X = Cl, Br, I) to form extended metal-containing arrays is described. It is shown that the self-assembly can lead to homochiral or heterochiral polymers or macrocycles, through self-recognition or self-discrimination of the ligand units, and the primary materials can further self-assemble through hydrogen bonding between amide substituents. In addition, the formation of macrocycles or polymers can be influenced by the presence or absence of excess mercury(II) halide, through a template effect, and mercury(II) halide inclusion complexes may be formed. In one case, an unusual polymeric compound was obtained, with 1 guest HgX2 molecule for every 12 mercury halide units in the polymer.

  DOI：

  10.1021/ic050097w