iron(II) tin(IV) fluoride | 27666-10-0

• 英文名称: iron(II) tin(IV) fluoride
• CAS: 27666-10-0
• 化学式: F₆Sn*Fe
• 分子量: 288.547
• InChiKey: XPZUKAXIPPVRHU-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  4-氨基-1,2,4-三氮唑 、 iron(II) tin(IV) fluoride 、 水 在 ascorbic acid 作用下， 以 乙醇 为溶剂， 以80%的产率得到[Fe(4-amino-1,2,4-triazole)3][hexafluorostannate]*water
  参考文献：
  名称：

  Iron(II) spin transition 1,2,4-triazole chain compounds with novel inorganic fluorinated counteranions

  摘要：

  New one-dimensional spin transition coordination polymers of formula [Fe(NH(2)trZ)(3)](AF(6)) center dot nH(2)O (A = Ti, Zr, Sn; NH(2)trz = 4-amino-1,2,4-triazole) have been synthesized in MeOH and EtOH media. These materials display an abrupt and hysteretic spin transition around 200 K as well as a reversible thermochromic effect on, cooling. A preliminary evaluation of the lattice dynamics in the high-spin and low-spin states is presented. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.11.009
• 作为产物：
  描述：

  iron(II) chloride tetrahydrate 、 ammonium hexafluorostannate(IV) 以 水 为溶剂， 生成 iron(II) tin(IV) fluoride
  参考文献：
  名称：

  Iron(II) spin transition 1,2,4-triazole chain compounds with novel inorganic fluorinated counteranions

  摘要：

  New one-dimensional spin transition coordination polymers of formula [Fe(NH(2)trZ)(3)](AF(6)) center dot nH(2)O (A = Ti, Zr, Sn; NH(2)trz = 4-amino-1,2,4-triazole) have been synthesized in MeOH and EtOH media. These materials display an abrupt and hysteretic spin transition around 200 K as well as a reversible thermochromic effect on, cooling. A preliminary evaluation of the lattice dynamics in the high-spin and low-spin states is presented. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.11.009

文献信息

• Etude du fluorostannate FeSnF6 par resonance Mössbauer des noyaux 57Fe et 119Sn
  作者：C Mirambet、L Fournes、J Grannec、P Hagenmuller

  DOI：10.1016/0025-5408(91)90069-x

  日期：1991.8

  The hexafluorostannate FeSnF6 undergoes at 728 +/- 5K a phase transition characterized by micro-DTA. A Mossbauer resonance investigation has been carried out over the 4.2 less-than-or-equal-to T less-than-or-equal-to 635 K temperature range on the two nuclei Fe-57 and Sn-119. From the study on the Fe-57 nucleus the existence of a high temperature phase transition has been ascertained. Evidence is given by the Mossbauer investigation on the Sn-119 nucleus that the dynamic lattice parameters of FeSnF6 and SnF4 are similar despite the structural differences.