| 701935-62-8

• CAS: 701935-62-8
• 化学式: BF₄*C₃₄H₄₆ClN₂O₂P₂Ru
• 分子量: 800.027
• InChiKey: UXUDWHKFITYJTF-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 silver tetrafluoroborate 以 二氯甲烷 为溶剂， 以77%的产率得到
  参考文献：
  名称：

  Supported organometallic complexes part 39: cationic diamine(ether–phosphine)ruthenium(II) complexes as precursors for the hydrogenation of trans-4-phenyl-3-butene-2-one

  摘要：

  Treatment of RuCl2(eta(1)-Ph2PCH2CH2OCH3)(2)(diamine) (1L(1)-1L(7)) with one equivalent of AgX (X = OTf, BF4) in CH2Cl2 results in the formation of the monocationic ruthenium(H) complexes [RuCl(eta(1)-Ph2PCH2CH2OCH3)(eta(2)-Ph2PCH2CH2OCH3)(diamine)]X-+(-) (2L(1)-2L(7)). These complexes were characterized by NMR, and mass spectroscopy as well as by elemental analyses, 2L(1) additionally by an X-ray structural analysis. Complex 2L(1) crystallizes in the monoclinic space group C2/c with Z = 8. The monocationic and neutral complexes were applied as catalysts in the selective hydrogenation of trans-4-phenyl-3-butene-2-one. With the exception of 1L(3)/1L(7) and 2L(3)/2L(7) all catalysts showed high activities and selectivities toward the hydrogenation of the carbonyl group under mild conditions. However, the activity of the cationic catalysts is only half of that of their neutral congeners. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.12.015