[(η5-C5H4SiH(CH3)2)Fe(η5-C5H4)]2SiMe2 | 1210377-43-7

• 英文名称: [(η5-C5H4SiH(CH3)2)Fe(η5-C5H4)]2SiMe2
• CAS: 1210377-43-7
• 化学式: C₂₆H₃₆Fe₂Si₃
• 分子量: 544.522
• InChiKey: LSDXAWHFKDOOQZ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  1,1'-bis(dimethylsilyl)-ferrocene 在 铂(0)-1,3-二乙烯-1,1,3,3-四甲基二硅氧烷 作用下， 以 xylene 为溶剂， 以30%的产率得到(η5-C5H4SiH(CH3)2)2Fe3((η5-C5H4)2SiMe2)2
  参考文献：
  名称：

  Unexpected Synthesis of Oligomeric (Dimethylsilyl)-Bridged Ferrocenes from the Desilylative Coupling of Tertiary 1,1′-Bis(dimethylsilyl)ferrocene

  摘要：

  The solvent-free, Pt-catalyzed desilylative coupling reaction of 1,1'-bis(dimethylsilyl)ferrocene (12) at elevated temperature leads to the elimination of one dimethylsilane unit and the concomitant oligomerization of ferrocenes with a single dimethylsilyl bridge in low to moderate yields. Air-and moisture-stable oils of the dimer (13) and trimer (14) species possessing dimethylsilyl bridges and terminal dimethyl-silane end groups have been isolated by preparative TLC and characterized by HR-MS, elemental analysis, and NMR spectroscopy.

  DOI：

  10.1021/om100041k