[Ag((2-py)CHNC10H6NCH(2-py))]PF6 | 497235-16-2

• 英文名称: [Ag((2-py)CHNC10H6NCH(2-py))]PF6
• CAS: 497235-16-2
• 化学式: C₂₂H₁₆AgN₄*F₆P
• 分子量: 589.228
• InChiKey: XJWNYPRFTWWWAI-AWFIFXRCSA-N

反应信息

• 作为产物：
  描述：

  六氟磷酸银 、 (2-py)CHNC10H6NCH(2-py) 以 氯仿 、 乙腈 为溶剂， 以58%的产率得到[Ag((2-py)CHNC10H6NCH(2-py))]PF6
  参考文献：
  名称：

  Homoleptic silver-bis(pyridine) coordination polymers: [Ag(L)2]·(PF6), [Ag(L)2]·(SbF6), [Ag(L)2]·(BF4), [Ag(L)]·(PF6), and [Ag(L)1.5]·(CF3SO3)·(H2O)2 {L= (4-py)–CH N–C10H6–N CH–(4-py); L= (2-py)–CH N–C10H6–N CH–(2-py); L= (3-py)–CH N–C14H12–N CH–(3-py)}

  摘要：

  Five homoleptic silver-bis(pyridine) coordination polymers, [Ag(L-1)2]center dot(FF6) (1), [Ag(L-1)(2))]center dot(SbF6) (2), [Ag(L-1)2]center dot(BF4) (3), [Ag(L-2)]center dot(PF6) (4), and [Ag(L-3)(1.5)]center dot(CF3SO3)center dot(H2O)(2) (5.(H2O)(2)), were prepared from AgX (X = PF6, SbF6, BF4, CF3SO3) and rigid bis(pyridine)-type linking ligands (L-1 = (4-py)-CH=N-C10H6-N=CH-(4-py); L-2 = (2-py)-CH=N-C10H6-N=CH-(2-py); L-3 = (3-py)-CH=N-C14H12-N=CH-(3-py)). Polymers 1-3 are isostructural and have the same non-interpenetrated, 3-D diamondoid framework, whose cavities are almost completely filled with the counterions. Polymer 4 is a 1-D chain polymer. Polymer 5 (H2O)2 is a 2-D alpha-arsenic-type polymer with a repeat unit of a 114-membered ring. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.06.019