[Ir(1,2-bis(diisopropylphosphino)ethane)(μ-Cl)]2 | 817578-14-6

• 英文名称: [Ir(1,2-bis(diisopropylphosphino)ethane)(μ-Cl)]2
• 英文别名: [Ir(dippe)(μ-Cl)]2
• CAS: 817578-14-6
• 化学式: C₂₈H₆₄Cl₂Ir₂P₄
• 分子量: 980.057
• InChiKey: LKZNRJDTGFCNCK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ir(1,2-bis(diisopropylphosphino)ethane)(μ-Cl)]2 以 氘代乙腈 为溶剂， 生成 [Ir(dippe)2]Cl*CH2Cl2
  参考文献：
  名称：

  Synthesis, structure and reactivity of [Ir(dippe)(μ-Cl)]2, [Ir(dippe)2][Ir(dippe)Cl2] and [Ir(dippe)2]Cl

  摘要：

  [Ir(COD)(mu-Cl)](2) reacts with two equivalents of 1,2-bis(diisopropylphosphino)ethane (dippe) to produce [Ir(dippe)(mu-Cl)](2) (1a) in yields that are dependent upon the solvent. Its single crystal X-ray structure shows a hinge angle theta of 132.2degrees, which is larger than in other reported iridium analogs, but smaller than in [Rh(dippe)(mu-Cl)](2) (1b). [Ir(dippe)(2)][Ir(dippe)Cl-2] (2), whose anion is without literature precedent, is an intermediate species in the conversion of 1a to [Ir(dippe)(2)]Cl (3). Complex 3 reacts with dihydrogen to produce [Ir(dippe)(2)H-2]Cl (4). (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.06.031
• 作为产物：
  描述：

  bis(1,5-cyclooctadiene)diiridium(I) dichloride 、 1,2-双(二-异丙基膦基)乙烷 以 乙腈 为溶剂， 以81.6%的产率得到[Ir(1,2-bis(diisopropylphosphino)ethane)(μ-Cl)]2
  参考文献：
  名称：

  Synthesis, structure and reactivity of [Ir(dippe)(μ-Cl)]2, [Ir(dippe)2][Ir(dippe)Cl2] and [Ir(dippe)2]Cl

  摘要：

  [Ir(COD)(mu-Cl)](2) reacts with two equivalents of 1,2-bis(diisopropylphosphino)ethane (dippe) to produce [Ir(dippe)(mu-Cl)](2) (1a) in yields that are dependent upon the solvent. Its single crystal X-ray structure shows a hinge angle theta of 132.2degrees, which is larger than in other reported iridium analogs, but smaller than in [Rh(dippe)(mu-Cl)](2) (1b). [Ir(dippe)(2)][Ir(dippe)Cl-2] (2), whose anion is without literature precedent, is an intermediate species in the conversion of 1a to [Ir(dippe)(2)]Cl (3). Complex 3 reacts with dihydrogen to produce [Ir(dippe)(2)H-2]Cl (4). (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.06.031