RuCl₂(dmso)₃(CH₃CN) | 668422-51-3

• 英文名称: RuCl₂(dmso)₃(CH₃CN)
• 英文别名: cis,fac-[RuCl2(dmso-S)3(acetonitrile)]；cis,fac-[RuCl2(dimethylsulfoxide-S)3(acetonitrile)]；cis,fac-[RuCl2(dmso)3(CH3CN)]
• CAS: 668422-51-3
• 化学式: C₈H₂₁Cl₂NO₃RuS₃
• 分子量: 447.434
• InChiKey: YRENJZNDFOVDGP-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  cis,fac-[RuCl2(dmso-S)3(indazole)] 、 乙腈 以 not given 为溶剂， 生成 RuCl₂(dmso)₃(CH₃CN)
  参考文献：
  名称：

  异构[RuCl2（dmso）2（吲唑）2]配合物：钌（II）介导的乙腈与1H-吲唑的偶联反应。

  摘要：

  抗肿瘤复合物反式-[Ru（III）Cl4（Hind）2]-（Hind =吲唑）与过量的二甲基亚砜（dmso）在丙酮中的反应得到复合物反式，反式，反式-[Ru（II）Cl2 （dmso）2（Hind）2]（1）。另两种同分异构体化合物，反式，顺式，顺式-[Ru（II）Cl2（dmso）2（Hind）2]（2）和顺式，顺式，顺式-[Ru（II）Cl2（dmso）2（Hind）2] （3）是在回流当量为2当量的顺式-[Ru（II）Cl（2）（dmso）（4）]时获得的。吲唑分别在乙醇和甲醇中的含量。异构体1和2与乙腈反应，生成反式-[Ru（II）Cl2（dmso）（Hind）{HN = C（Me）ind}]。CH3CN（4.CH3CN）和反式-顺式[Ru（II） ）Cl2（dmso）2 {HN = C（Me）ind}]。H2O（5.H2O）分别包含由乙腈C三键N基团插入环的N1-H键而形成的环状

  DOI：

  10.1039/b503650j

文献信息

• Ru(<scp>ii</scp>)- and Ru(<scp>iv</scp>)-dmso complexes catalyze efficient and selective aqueous-phase nitrile hydration reactions under mild conditions
  作者：Manoj Trivedi、Santosh Kumar Dubey、Gurmeet Kaur、Nigam P. Rath

  DOI：10.1039/d1nj03041h

  日期：——

  ruthenium(IV)-dmso complexes [RuCl2(dmso)2(NH3)(CH3CN)] (1), [RuCl2(dmso)3(CH3CN)] (2), and [RuCl2(dmso)3(NH3)]·PF6·Cl (3) have been synthesized and characterized using elemental analyses, IR, 1H and 31P NMR, and electronic absorption spectroscopy. The molecular structures of complexes 1–3 were determined crystallographically. The reactivity of complexes 1–3 has been tested for aqueous-phase nitrile hydration

  新型水溶性钌( II )-和钌( IV )-dmso配合物[RuCl 2 (dmso) 2 (NH 3 )(CH 3 CN)] ( 1 ), [RuCl 2 (dmso) 3 (CH 3 CN) ] ( 2 ) 和[RuCl 2 (dmso) 3 (NH 3 )]·PF 6 ·Cl ( 3 ) 已合成并使用元素分析、IR、1 H 和31 P NMR 以及电子吸收光谱进行表征。配合物1 – 3的分子结构是通过晶体学确定的。配合物1-3的反应性已在 60 °C 空气中进行水相腈水合测试，相应的酰胺衍生物显示出良好的效率和选择性。使用 complex 3实现最佳性能. 使用各种芳族、烷基和乙烯基腈获得 56-99% 的酰胺转化率。该反应耐受羟基、硝基、溴、甲酰基、吡啶基、苄基、烷基和烯属官能团。通过简单的倾析从水相催化剂中分离出酰胺。检查了低至 0.0001 mol% 的催化剂负载，并观察到高达
• Synthesis of ruthenium(II) monosubstituted squarates: 1. Procedural considerations
  作者：Patrice M.T. Piggot、Lincoln A. Hall、Andrew J.P. White、David J. Williams

  DOI：10.1016/s0020-1693(03)00424-9

  日期：2004.1

  Attempted syntheses of ruthenium(II) monosubstituted squarate complexes in acetonitrile using cis-[RuCl2(dmso)(4)] and anisole-, methoxy-, methyl- and diphenylamino-squarate ligands, respectively, resulted in the formation in each case of the monomer cis, fac-Ru(CH3CN)Cl-2(dmso)(3) (1) with the ruthenium atom in a distorted octahedral environment. A second crop of crystals harvested from the reaction with the methoxysquarate ligand was identified as the oxalato-bridged dimer [cis-(CH3CN)(Cl)(dmso)(2)Ru}(2)(mu-C2O4)] (2). When cis-[RuCl2(dmso)(4)] and methylsquarate were reacted in aqueous solution instead of acetonitrile, the dimer [(Cl)(dmso)(3)Ru 2(mu-C2O4)] (3) was produced. The dimers 2 and 3 are formed from oxidation/ring opening of the methoxy- and methyl-squarate ligands, respectively. Use of the salts of these ligands instead of their non-ionised forms under different reaction conditions, afforded [Na] fac-[RuCl3(dmso)(3)] (4) and [(C4H9)(4)N](2)[(C4O4)(C4H2O4)(2)] (7), respectively, which were shown to be products of competing reactions. The information acquired from these failed attempts has provided the basis for the development of a strategy to overcome these problems and lead to a successful synthetic route to ruthenium(II) monosubstituted squarates. (C) 2003 Elsevier B.V. All rights reserved.