bis(bis(2-diphenylphosphinoethyl)phenylphosphine)trisilver(I) hexafluoroborate | 223396-00-7

• 英文名称: bis(bis(2-diphenylphosphinoethyl)phenylphosphine)trisilver(I) hexafluoroborate
• CAS: 223396-00-7
• 化学式: BF₄*C₃₄H₃₃AgP₃
• 分子量: 729.23
• InChiKey: LXNSXOWXRUONJR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  双(2-二苯基膦乙基)苯基磷 、 silver tetrafluoroborate 以 二氯甲烷 为溶剂， 以93%的产率得到bis(bis(2-diphenylphosphinoethyl)phenylphosphine)trisilver(I) hexafluoroborate
  参考文献：
  名称：

  Mueller, Thomas E.; Pleier, Anna-Katharina, Journal of the Chemical Society, Dalton Transactions, 1999, # 4, p. 583 - 587

  摘要：

  DOI：

文献信息

• Tripodal polyphosphine ligands in silver (I) coordination chemistry: Mononuclear cf. polynuclear complex dependence vis-a-vis counterion and ligand to metal ratio
  作者：Effendy、Claudio Pettinari、Massimo Ricciutelli、Brian W. Skelton、Allan H. White、Riccardo Pettinari

  DOI：10.1016/j.ica.2005.06.041

  日期：2005.9

  1:2, 1:1, 3:2 and 6:2 AgX:L adducts (where L is a tridentate phosphine, in detail: 1,1,1-tris(diphenylphosphinomethyl)ethane (Metriphos) and bis(2-diphenylphosphinoethyl)phenylphosphine (Ph-triphos), X = O3SCF3, O3SCH3, BF4 or O2CCF3) have been synthesized and characterized by IR, NMR (H-1, P-31 and F-19) and ESI MS spectroscopy. The stoichiometry of the complexes is strongly dependent on the ligand to metal ratio employed and also on the nature of the counterion. P-31 NMR (solution) data also show the complexes existing in solution, in some cases, however, disproportionating to adducts of different nuclearity. Oligonuclear species have been detected through ESI MS spectroscopy that has been demonstrated as a powerful tool for the identification of the solution species. AgBF4:Me-triphos (1:2) has been structurally characterized as [Ag(P,P'-Me-triphos)(2)](BF4) (.) H2O (.) 7/2 MeOH, while Ag(O3SCF3): Ph-triphos: H2O (6:2:4) is a spectacular two-dimensional polymer. (c) 2005 Elsevier B.V. All rights reserved.