An Organometallic Tetranuclear Complex of μ4-PO4: [{(Cp*Cr)2(μ-OMe)2}2(μ4-PO4)]X (X = I, PF6)
摘要:
The first discrete organometallic tetranuclear mu(4)-PO4 complex, [{Cp*Cr)(2)(mu-OMe)(2)}(2)(Y-4-PO4)](+) (5; Cp*=eta(5)-C5Me5), was isolated as the iodide and PF6 salts from the reaction between NaH2PO4 and [Cp*Cr(mu-OMe)I], (2), which was derived from thiolate methylation of [Cp*Cr{eta(3)-HN((CHCH2S)-C-2)(2)}] (1) with MeI in MeOH.