{2,5-bis-[3-(1H-1,3-imidazol-1-yl-methyl)phenyl]-1,3,4-oxadiazole}-dichloridocobalt(II) | 1318765-01-3

• 英文名称: {2,5-bis-[3-(1H-1,3-imidazol-1-yl-methyl)phenyl]-1,3,4-oxadiazole}-dichloridocobalt(II)
• CAS: 1318765-01-3
• 化学式: C₂₂H₁₈Cl₂CoN₆O
• 分子量: 512.324
• InChiKey: PVCHWLQTGWGDQF-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  cobalt(II) chloride hexahydrate 、 2,5-bis-[3-(1H-1,3-imidazol-1-ylmethyl)phenyl]-1,3,4-oxadiazole 以 甲醇 为溶剂， 以74%的产率得到{2,5-bis-[3-(1H-1,3-imidazol-1-yl-methyl)phenyl]-1,3,4-oxadiazole}-dichloridocobalt(II)
  参考文献：
  名称：

  A novel 18-membered metallocycle in {2,5-bis[3-(1H-1,3-imidazol-1-ylmethyl)phenyl]-1,3,4-oxadiazole}dichloridocobalt(II)

  摘要：

  The title molecular complex, [CoCl(2)(C(22)H(18)N(6)O)], features a novel 18-membered Co-containing metallocycle. The Co(II) atom lies in a fairly regular tetrahedral geometry defined by two imidazole N-atom donors from one 2,5-bis[3-(1H-1,3-imidazol-1-ylmethyl)phenyl]-1,3,4-oxadiazole (L) ligand and two chloride anions. The coordinating orientation of the L ligand plays an important role in constructing the metallocycle complex. The complexes form a three-dimensional supramolecular assembly via nonclassical C-H center dot center dot center dot Cl and C-H center dot center dot center dot N hydrogen bonds and pi-pi interactions.

  DOI：

  10.1107/s0108270110016689