| 74050-80-9

• CAS: 74050-80-9
• 化学式: C₂₀H₂₂Br₂FeN₄O₂*F₆P
• 分子量: 711.039
• InChiKey: VWMOLLYJORSJTA-AREIFDNXSA-L

反应信息

• 作为反应物：
  描述：

  manganese(II) chloride tetrahydrate 、 silver tris(oxalato)chromate(III) 、 以 甲醇 、 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Multifunctional Magnetic Materials Obtained by Insertion of Spin-Crossover Fe^III Complexes into Chiral 3D Bimetallic Oxalate-Based Ferromagnets

  摘要：

  The syntheses, structures, and magnetic properties of compounds of formula [Fe-III(5-Clsal(2)-trien)][(MnCrIII)-Cr-II(ox)(3)] center dot 0.5(CH3NO2) (1), [Fe-III(5-Brsal(2)-trien)][(MnCrIII)-Cr-II(ox)(3)] (2), and [In-III(5-Clsal(2)-trien)][(MnCrIII)-Cr-II(ox)(3)] (3) are reported. The structure of the three compounds, which crystallize in the orthorhombic P2(1)2(1)2(1) chiral space group, presents a 3D chiral anionic network formed by Mn-II and Cr-III ions linked through oxalate ligands with inserted [Fe-III(5-Clsal(2)-trien)](+), [Fe-III(5-Brsal(2)-trien)](+), and [In-III(5-Clsal(2)-trien)](+) cations. The magnetic properties indicate that the three compounds undergo long-range ferromagnetic ordering at ca. 5 K. On the other hand, the inserted Fe-III cations undergo a partial spin crossover in the case of 1 and 2.

  DOI：

  10.1021/ic201293f