[(η5-1,2,3,4,7-pentamethylindenyl)Rh(1,5-cyclooctadiene)](1+) | 1002356-78-6

• 英文名称: [(η5-1,2,3,4,7-pentamethylindenyl)Rh(1,5-cyclooctadiene)](1+)
• CAS: 1002356-78-6
• 化学式: C₂₂H₂₉Rh
• 分子量: 396.378
• InChiKey: JYFIGSFCEWXABY-GHDUESPLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [(η5-1,2,3,4,7-pentamethylindenyl)Rh(1,5-cyclooctadiene)] 在 (N(C₄H₉)4)(PF₆) 作用下， 以 二氯甲烷 为溶剂， 生成 [(η5-1,2,3,4,7-pentamethylindenyl)Rh(1,5-cyclooctadiene)](1+)
  参考文献：
  名称：

  (1,2,3,4,7-Pentamethylindenyl)rhodium complexes with arene ligands

  摘要：

  The reaction of (eta(5)-C9H2Me5)Rh(1,5-C8H12) (1) with I-2 gives the iodide complex [(eta(5)-C9H2Me5)RhI2](2) (2). The solvate complex [(eta 5-C9H2Me5)Rh(MeNO2)(3)](2+) (generated in situ by treatment of 2 with Ag+ in nitromethane) reacts with benzene and its derivatives giving the dicationic arene complexes [(eta(5)-C9H2Me5)Rh(arene)](2+) [arene = C6H6 (3a), C6Me6 (3b), C6H5OMe (3c)]. Similar reaction with the borole sandwich compound CpRh(eta(5)-C4H4BPh) results in the arene-type complex [CpRh(mu-eta(5):eta(6)-C4H4BPh)Rh(eta(5)-C9H2Me5)](2+) (4). Treatment of 2 with CpT1 in acetonitrile affords cation [(eta(5)-C9H2Me5)RhCp](broken vertical bar) (5). The structure of [3c](BF4)(2) was determined by X-ray diffraction. The electrochemical behaviour of complexes prepared was studied. The rhodium-benzene bonding in series of the related complexes [(ring)Rh(C6H6)](2+) (ring = Cp, Cp*, C9H7, C9H2Me5) was analyzed using energy and charge decomposition schemes. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.10.006