| 209854-64-8

• CAS: 209854-64-8
• 化学式: C₂₃H₄₉Cl₃O₄S₂Sn
• 分子量: 678.841
• InChiKey: UBONMUMGEFDXBF-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  正丁基亚砜 、 3-(三氯锡烷基)丙酸丁酯 以 乙醚 为溶剂， 以68%的产率得到
  参考文献：
  名称：

  Synthesis and characterization of β-alkoxycarbonylethyltin trichloride complexes with dibutylsulfoxide. Crystal structure of CH3CH2OCOCH2CH2SnCl3 · (n-C4H9)2SO

  摘要：

  The organotin(IV) complexes, ROCOCH2CH2SnCl3 . nL (R = Me, Et, n-Pr, Allyl, n-Bu, i-Bu; n = 1, 2; L = dibutylsulfoxide) have been synthesized and characterized. The spectral data (IR, H-1 and C-13 NMR) indicate that the 1:1 (n = 1) and 1:2 (n = 2) complexes are all hexa-coordinated tin compounds, and the carbonyl oxygen is coordinated to intramolecular tin atom in 1:1 complexes and is free in 1:2 complexes. The crystal structure of EtOCOCH2CH2SnCl3 . L shows that the fin atom adopts a distorted octahedral geometry via the oxygens of dibutylsulfoxide and intramolecular carbonyl group to tin coordination. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(97)00378-1