| 1211547-83-9

• CAS: 1211547-83-9
• 化学式: C₃₉H₅₁NO₂PRh
• 分子量: 699.719
• InChiKey: NWDPALYODQDYAP-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  2,6-di(propan-2-yl)-N-[2-[(2,4,6-tritert-butylphenyl)phosphanylidenemethyl]phenyl]aniline 、 di(rhodium)tetracarbonyl dichloride 在 triethylamine 作用下， 以 苯 为溶剂， 以97%的产率得到
  参考文献：
  名称：

  Synthesis of rhodium–carbonyl complexes bearing a novel P,N-chelating ligand of Schiff-base type

  摘要：

  Schiff-base type N,P-chelating ligands, phosphorus analogues of imino-anilido ligands, were designed and synthesized as a new type of ligands toward transition metals, and the rhodium-carbonyl complexes bearing the novel imino-phosphido and phosphaalkenyl-anilido ligands were synthesized as stable crystalline compounds. Their structures were definitively revealed by X-ray crystallographic analysis, showing the unique electronic features of the ligands. In addition, the effective trans-influence of the phosphorus atom was suggested on the basis of the structural parameters and spectroscopic features of the isolated complexes. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.06.043