| 1258605-11-6

• CAS: 1258605-11-6
• 化学式: C₃₅H₄₃Cl₂FeN₂P
• 分子量: 649.467
• InChiKey: GBVMWJIBRXVBKI-OESBJFCKSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-(mesitylimino)acenaphthylene-1-one 、 iron(II) chloride 、 (2-Aminoethyl)-dicyclohexylphosphin 以 正丁醇 为溶剂， 以72%的产率得到
  参考文献：
  名称：

  Oligomerization of Ethylene Using New Tridentate Iron Catalysts Bearing α-Diimine Ligands with Pendant S and P Donors

  摘要：

  Stoichiometric Schiff base condensations of sterically bulky primary amines with acenaphthene quinone yield isolable monoimines In the presence of iron(II) chloride the remaining ketone reacts with a second primary amine bearing a pendant donor atom to give asymmetric tridentate a diimine complexes that possess remarkable structural variability A series of NNP and NNS tridentate iron(II) complexes are prepared these coordination compounds become active catalysts for ethylene oligomerization when activated with methylalumoxanes X ray crystallographic studies of the precatalyst complexes confirm that the ligand binds in a tridentate fashion Correlations between the precatalyst solid state structures and catalyst activity and a olefin product distribution are explored

  DOI：

  10.1021/om1007743