Molybdenum, dibromotricarbonylbis(triphenylphosphine)- | 135820-69-8

• 英文名称: Molybdenum, dibromotricarbonylbis(triphenylphosphine)-
• 英文别名: Mo(CO)3(PPh3)2Br2
• CAS: 135820-69-8；17250-41-8
• 化学式: C₃₉H₃₀Br₂MoO₃P₂
• 分子量: 864.361
• InChiKey: RPKDTHPHHFEUIV-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  Molybdenum, dibromotricarbonylbis(triphenylphosphine)- 以 二氯甲烷 为溶剂， 生成 trans-MoBr2(CO)2(PPh3)2
  参考文献：
  名称：

  Herrick, Richard S.; Peters, Christopher H.; Duff Jr., Ronald R., Inorganic Chemistry, 1988, vol. 27, # 13, p. 2214 - 2219

  摘要：

  DOI：
• 作为产物：
  描述：

  molybdenum hexacarbonyl 在 P(C₆H₅)3 、 Br₂ 作用下， 以 二氯甲烷 为溶剂， 以86%的产率得到Molybdenum, dibromotricarbonylbis(triphenylphosphine)-
  参考文献：
  名称：

  Stabilization of RN:NN:PR3. Preparation and structural characterization of stable tetraarylphosphazide complexes containing molybdenum and tungsten

  摘要：

  DOI：

  10.1021/ic00135a068

文献信息

• Bromination of molybdenum carbonyls revisited: oxo complexes and routes to new materials chemistry
  作者：James R. Backhouse、Helen M. Lowe、Ekkehard Sinn、Shigeru Suzuki、Simon Woodward

  DOI：10.1039/dt9950001489

  日期：——

  The use of in situ [MoBr(mu-Br)(CO)(4)}(2)] led to considerably improved preparations of [MoBr2(CO)(3)(PPh(3))(2)] for which the rate of decarbonylation to [MoBr2(CO)(2)(PPh(3))(2)] is greatly increased by refluxing under reduced pressure (15-20 mmHg). Attempts to prepare [MoBr2- (CO)(2)P(C6H11)(3)}(2)] by Br-2 addition to cis- or trans-[Mo(CO)(4)P(C6H11)(3)}(2)] led to [HP(C6H11)(3)][Mo-(=0)Br(4)L] [L = OP(C6H11)(3) or H2O]. The OP(C6H11)(3) complex maybe used as a catalyst for the epoxidation of cyclohexene or for the addition of singlet oxygen to alpha-terpinene (1-isopropyl-4-methylcyclohexa-1, 3-diene). The species [HP(C6H11)(3)] [Mo(=0)Br-4OP(C6H11)(3)}] was adsorbed onto sodium montmorillonite in a new type of reaction for sodium montmorillonite involving multiple abstractions of NaBr from the complex anion. In solution [HP(C6H11)(3)][Mo(=0)Br-4OP(C6H11)(3)}] also decomposes to crystalline [Mo(=0)(2)Br-2OP(C6H11)(3)}(2)] which is monoclinic, space group C2/c [a = 27.15(5), b = 8.486(8), c = 18.49(2) Angstrom, beta = 110.94(7)degrees].
• Molybdenum(II) and tungsten(II) M(Co)(RC2R')L2X2 alkyne complexes
  作者：P. B. Winston、S. J. N. Burgmayer、T. L. Tonker、J. L. Templeton

  DOI：10.1021/om00139a032

  日期：1986.8.1
• Greenwood, N. N.; Kennedy, J. D.; Macpherson, I., Zeitschrift fur Anorganische und Allgemeine Chemie
  作者：Greenwood, N. N.、Kennedy, J. D.、Macpherson, I.、Thornton-Pett, M.

  DOI：——

  日期：——
• Murphy Simmons, Anne-Marie; Mills, Nancy S.; Iyer, Savithri R., Inorganica Chimica Acta, 1986, vol. 116, p. 43 - 46
  作者：Murphy Simmons, Anne-Marie、Mills, Nancy S.、Iyer, Savithri R.

  DOI：——

  日期：——