[[1-(diphenylphosphino)cyclopropane carbonitrile]pentamethylcyclopentadienyl] rhodium dichloride | 845291-68-1

• 英文名称: [[1-(diphenylphosphino)cyclopropane carbonitrile]pentamethylcyclopentadienyl] rhodium dichloride
• CAS: 845291-68-1
• 化学式: C₂₆H₂₉Cl₂NPRh
• 分子量: 560.308
• InChiKey: ZLBKHCWMAQHNFA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer 、 1-(diphenylphosphino)cyclopropane carbonitrile 以 二氯甲烷 为溶剂， 以76%的产率得到[[1-(diphenylphosphino)cyclopropane carbonitrile]pentamethylcyclopentadienyl] rhodium dichloride
  参考文献：
  名称：

  Novel functionalised P-ligands: advances and application

  摘要：

  Novel endo- and exocyclic phosphine ligands possessing different functionalities obtained by reduction of the P=O precursors with desired stereochemistry are discussed. The diastereoselective deoxygenation including the catalytic reduction processes, the factors defining the reactivity and the role of the substituents on the stability of phosphorus atom configuration in a series of 3-aryl-3-phosphabicyclo[3.1.0]hexanes are reported. The complexation features of the ligands with Rh(III) and Pd(II) were examined and Rh(III) complexes were tested in styrene hydroformylation showing the structure-activity dependence. (c) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.09.030