di(μ-O)di[nitrato[N-(5-chloro-2-oxy-1-benzylidene)-N'-α-oxybenzylidenehydrazine]copper] | 746619-83-0

• 英文名称: di(μ-O)di[nitrato[N-(5-chloro-2-oxy-1-benzylidene)-N'-α-oxybenzylidenehydrazine]copper]
• CAS: 746619-83-0
• 化学式: C₂₈H₂₀Cl₂Cu₂N₆O₁₀
• 分子量: 798.499
• InChiKey: XCMNDUJIUVSCSM-XNQQGXESSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  5-chlorosalicylidene-benzoyl hydrazide 、 copper(II) nitrate 以 乙醇 为溶剂， 以72%的产率得到di(μ-O)di[nitrato[N-(5-chloro-2-oxy-1-benzylidene)-N'-α-oxybenzylidenehydrazine]copper]
  参考文献：
  名称：

  Coordination Compounds of Copper(II) with Benzoylhydrazones of Substituted Salicylaldehydes

  摘要：

  Benzoylhydrazones of 5-nitro- (H2L1), 3-nitro- (H2L2), 5-chloro- (H2L3), 5-bromo- (H2L4), and 3,5-dibromosalicylaldehydes (H2L5) react in ethanol with copper acetate to form complexes CuL1-5. In the presence of amines (A = C5H5N, 3-CH3C5H4N), the above reactions give complexes CuL(1-5)A (.) nH(2)O (n = 0, 1). When cuprous bromide or nitrate and benzoylhydrazone H(2)L3 were used as starting materials, complexes Cu(HL3)X (X = Br-, NO3) were isolated. The resulting complexes all are polynuclear structures in which azomethines H2H1-5 behave as tridentate O,N,O-ligands. Thermolysis of the complexes involves the stages of dehydration (70-90degreesC), deaquation (120-150degreesC) or deamination (150-180degreesC), and complete thermal decomposition (350-500degreesC).

  DOI：

  10.1023/b:rugc.0000016032.80593.ec