| 93530-19-9

• CAS: 93530-19-9
• 化学式: Br*C₉H₉MnN₃O₃
• 分子量: 342.031
• InChiKey: SWWXMVMNJPSNSQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Besecker; Day; Klemperer, Inorganic Chemistry, 1985, vol. 24, # 1, p. 44 - 50

  摘要：

  DOI：

文献信息

• Manganese complexes of the pentaphenylcyclopentadienyl ligand
  作者：Leslie D. Field、Taian He、Paul Humphrey、Anthony F. Masters、Peter Turner

  DOI：10.1016/j.poly.2005.08.055

  日期：2006.5

  The preparation and characterisation of [Mn(eta(5)-C5Ph5)(CO)(3)] (1), [Mn(eta(5)-C5Ph5)(CO)(2)(PMe2Ph)] (2), and [Mn(eta(5)-C-5(p-tol)(5))(CO)(3)] (3) are described; these complexes are the first reported fully characterised C5Ar5- derivatives of Group 7. Compounds (1) and (3) are reversibly oxidised at +0.98 and +0.89 V, respectively (versus Fc(+/0)), significantly more positive than the oxidation of the analogous [Mn(eta(5)-C5H5)(CO)(3)]. Single crystal X-ray diffraction studies of (1) and (2) (refined to R-1(F) 0.0967, wR(2)(F-2) 0.2971 and R-1(F) 0.0472, wR(2)(F-2) 0.1356, respectively) are also reported. (C) 2005 Elsevier Ltd. All rights reserved.