[B(OEt)3]3(tris(((2-oxybenzyl)amino)ethyl)amine) | 212757-69-2

• 英文名称: [B(OEt)3]3(tris(((2-oxybenzyl)amino)ethyl)amine)
• CAS: 212757-69-2
• 化学式: C₃₉H₅₇B₃N₄O₉
• 分子量: 758.336
• InChiKey: CKMWVNQLTNGUPY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  硼酸三乙酯 、 tris[2-(N-salicylideneamino)ethyl]amine 以 甲苯 为溶剂， 以63%的产率得到[B(OEt)3]3(tris(((2-oxybenzyl)amino)ethyl)amine)
  参考文献：
  名称：

  Syntheses and reactions of Saltren–Group 13 complexes

  摘要：

  Neutral Group 13 combinations with the Saltren ligand (tris(((2-hydroxybenzyl)amino)ethyl)amine)) have been prepared and their reactivity explored. The majority of the compounds are of formula Saltren(MR2)(3) where M = B; R = OMe (1), Oft (2), (OPr)-Pr-n (3); M = Al; R = Me (4), Et (5), Bu-i (6) and R = Et for M = Ga (7) and In (8). Mono-, [SaltrenHAlMe](n) (9), and tetra-metallic, Saltren(AlMe2)(3)-AlMe3 form when one and four equivalents of AlMe3 are added to the ligand. Compound 9 can be converted to 4 by the addition of two or three additional molecules of AlMe3. Compounds 1 and 4 form unique zwitterionic compounds, [SaltrenH(3){M(OSiPh3)(3)}(3)] (M = B (11) and Al (12) when combined with six equivalents of Ph3SiOH. Attempts to prepare those of formula Saltren{MR(OSiPh3)}(3) where M = B and Al led to an inseparable mixture of compounds. All of the compounds were characterized by standard techniques and, in the case of 1, 4, 7 and 12, by X-ray crystallography. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00544-0