[FeCl2(bis(4-(pyridin-2-yl)pyrimidin-2-yl)sulfane)] | 1231156-70-9

• 英文名称: [FeCl2(bis(4-(pyridin-2-yl)pyrimidin-2-yl)sulfane)]
• CAS: 1231156-70-9
• 化学式: C₁₈H₁₂Cl₂FeN₆S
• 分子量: 471.152
• InChiKey: CTEJRJDBGLYVFM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  di[4-(pyridin-2-yl)pyrimidinyl]disulfide 、 iron(II) chloride 以 not given 为溶剂， 以81%的产率得到[FeCl2(bis(4-(pyridin-2-yl)pyrimidin-2-yl)sulfane)]
  参考文献：
  名称：

  Diverse reactions of S–S function under metal-mediated and metal-free thermolysis conditions

  摘要：

  Parallel comparative studies on reactivities of S-S function in 2-ppds (2-ppds = bis(4-(pyridin-2-yl)pyrimidin-2-yl)disulfane) have been carried out under the same thermolysis conditions. In the presence of FeCl(2), thermolysis reaction of 2-ppds in the MeOH/CH(2)Cl(2) mixture results in a mononuclear compound [FeCl(2)(2-pps)] with newly generated organic ligand 2-pps (2-pps = bis(4-(pyridin-2-yl)pyrimidin-2-yl)sulfane). In the absence of FeCl(2), the result of solvolysis depends upon the conditions. Thus, in pure MeOH, 2-ppds partially converts into a mixture of S-(4-pyridin-2-yl)pyrimidin-2-yl (4-pyridin-2-yl)pyrimidine-2-sulfonothioate (2-ppst) and 2-pps, while in a MeOH/CH(2)Cl(2) mixture, 2-(chloromethylthio)-4-(pyridin-2-yl)pyrimidine (2-ppct) is the main product. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2009.10.009