tetracarbonyl[(2,3-diphenyl-κC1')(benzo[g]quinoxaline-κN)]manganese(I) | 870190-62-8

• 英文名称: tetracarbonyl[(2,3-diphenyl-κC1')(benzo[g]quinoxaline-κN)]manganese(I)
• CAS: 870190-62-8
• 化学式: C₂₈H₁₅MnN₂O₄
• 分子量: 498.376
• InChiKey: ZXLUBLRREVGVNB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  benzylpentacarbonylmanganese 、 2,3-二苯基苯并[g]喹喔啉 以 正己烷 、 苯 为溶剂， 以51%的产率得到tetracarbonyl[(2,3-diphenyl-κC1')(benzo[g]quinoxaline-κN)]manganese(I)
  参考文献：
  名称：

  Unprecedented ligand anti-bis-benzylation upon thermolytic treatment of 2,3-diphenylbenzo[g]quinoxaline with (η1-benzyl) pentacarbonylmanganese

  摘要：

  The treatment of 2.3-diphenylbenzo[g]quinoxaline with PhCH2Mn(CO)(5) in boiling n-heptane affords substantial amounts of a biscyclomanganated 5,10-anti-bis-benzylation product, which structure was assessed by X-ray diffraction analysis. In toluene and under similar experimental conditions, the formation of the latter is inhibited and the major product is the corresponding bis-cyclo-manganated 2,3-diphenylbenzo[g]quinoxaline. The bis-benzylation reaction seemingly results from a trapping of benzyl radicals formed upon homolytic cleavage of the C-Mn bond in PhCH2Mn(CO)(5) by the metallated 2,3-diphenylbenzo[g]quinoxaline. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.07.077