diferrocenyl(ethyl)phosphine oxide monohydrate | 426847-39-4

• 英文名称: diferrocenyl(ethyl)phosphine oxide monohydrate
• CAS: 426847-39-4
• 化学式: C₂₂H₂₃Fe₂OP*H₂O
• 分子量: 464.107
• InChiKey: OVZCMZCKQSRUFG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  diferrocenyl(ethyl)phosphine 在 air 作用下， 以 neat (no solvent) 为溶剂， 生成 diferrocenyl(ethyl)phosphine oxide monohydrate
  参考文献：
  名称：

  SYNTHESIS AND CHARACTERIZATION OF SOME ALKYL(DIFERROCENYL)PHOSPHINES AND ALKYL(DIFERROCENYL)PHOSPHINE OXIDES

  摘要：

  Reaction of ferrocene with alkyldichlorophosphines (RPCl2, R =Me, Et, t-Bu) in the presence of aluminum chloride produces diferrocenyl(alkyl)phosphines (Fc(2)PR, (1a)-(3a), R = Me, Et, t-Bu) and diferrocenyl(alkyl) phosphine oxides Fc(2)P(O)R, (1b)-(3b) in low yields. Diferrocenyl(ethyl)phosphine oxide (2b) crystallizes in the PI space group with one equivalent of water in the crystal. Compounds (1a)-(3a) are oxidized at lower potentials than the corresponding phenyl derivative, Fc(2)PPh. Cyclic voltammetry of (1a)-(3a) indicates that the first oxidation is irreversible. The corresponding diferrocenyl(alkyl)phosphine oxides (1b)-(3b) are more difficult to oxidize than (1a)-(3a) but show two reversible oxidations separated by 140-160mV.

  DOI：

  10.1081/sim-120013149