(E)-2-methoxy-4-(naphthalen-1-yliminomethyl)phenyl adamantane-1-carboxylate | 1240894-51-2

• 英文名称: (E)-2-methoxy-4-(naphthalen-1-yliminomethyl)phenyl adamantane-1-carboxylate
• CAS: 1240894-51-2
• 化学式: C₂₉H₂₉NO₃
• 分子量: 439.554
• InChiKey: BJQQWHFHCYWURO-UXHLAJHPSA-N

反应信息

• 作为产物：
  描述：

  1-萘胺 、 tricyclo[3.3.1.1^3,7]decane-1-carboxylic acid 4-formyl-2-methoxyphenyl ester 以 甲醇 为溶剂， 以87%的产率得到(E)-2-methoxy-4-(naphthalen-1-yliminomethyl)phenyl adamantane-1-carboxylate
  参考文献：
  名称：

  Synthesis and properties of (E)-4-[alkyl(aryl)iminomethyl]-2-methoxy(ethoxy)phenyl adamantane-1-carboxylates

  摘要：

  Condensation of 4-formyl-2-methoxy(ethoxy)phenyl adamantane-1-carboxylates with aliphatic, cycloaliphatic, and aromatic amines gave the corresponding adamantane-containing Schiff bases as E isomers with respect to the CH=N azomethine bond. The reaction of 2-methoxy-4-(naphthalen-2-yliminomethyl)phenyl adamantane-1-carboxylate with cyclohexane-1,3-dione and dimedone led to the formation of 2-methoxy-4-(11-oxo-7,8,9,10,11,12-hexahydrobenzo[a]acridin-12-yl)phenyl adamantane-1-carboxylates. Quantum-chemical calculations of the energies of formation of E and Z isomers of some of the synthesized Schiff bases were performed.

  DOI：

  10.1134/s107042801004010x