4,4-dimethyl-1,3,5,7-tetramethyl-2,6-diethyl-8H-4-bora-3a,4a-diaza-s-indacene | 1219485-12-7

• 英文名称: 4,4-dimethyl-1,3,5,7-tetramethyl-2,6-diethyl-8H-4-bora-3a,4a-diaza-s-indacene
• CAS: 1219485-12-7
• 化学式: C₁₉H₂₉BN₂
• 分子量: 296.264
• InChiKey: IRXQXTNBZRWQOU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2,6-diethyl-4,4-difluoro-1,3,5,7-tetramethyl-8H-4-bora-3a,4a-diaza-s-indacene 、 甲基溴化镁 以 乙醚 为溶剂， 反应 3.0h， 以98%的产率得到4,4-dimethyl-1,3,5,7-tetramethyl-2,6-diethyl-8H-4-bora-3a,4a-diaza-s-indacene
  参考文献：
  名称：

  Conversion of 4,4-Difluoro-4-bora-3a,4a-diaza-s-indacenes (F-BODIPYs) to Dipyrrins with a Microwave-Promoted Deprotection Strategy

  摘要：

  4,4-Difluoro-4-bora-3a,4a-diaza-s-indacenes (F-BODIPYs) have been deprotected to give the corresponding free-base dipyrrins by heating a solution of the F-BODIPY In tert-butanol under 600 W of microwave irradiation in the presence of 6 equiv of potassium tert-butoxide for 40 min at 92 degrees C. Investigations of BODIPY modification at the meso position have also been undertaken and a meso-butyl product has been isolated.

  DOI：

  10.1021/ol902908j