[Mn(CO)4(1,2-bis(diphenylphosphino)ethane)](BF4) | 145088-67-1

• 英文名称: [Mn(CO)4(1,2-bis(diphenylphosphino)ethane)](BF4)
• 英文别名: {(CO)4(1,2-bis(diphenylphosphino)ethane)Mn}BF4；[(CO)4Mn(1,2-bis(diphenylphosphino)ethane)]BF4
• CAS: 145088-67-1
• 化学式: BF₄*C₃₀H₂₄MnO₄P₂
• 分子量: 652.208
• InChiKey: KDCJHUYRIRBQOM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Mn(CO)4(1,2-bis(diphenylphosphino)ethane)](BF4) 在 NaN₃ 作用下， 以 甲醇 为溶剂， 以86-90的产率得到[(CO)3Mn(I)(1,2-bis(diphenylphosphino)ethane)(NCO)]
  参考文献：
  名称：

  The synthesis of alkoxycarbonyl, carbamoyl and isocyanato complexes, fac-M(CO)3(P-P)Z [M = Mn, Re; P-P = dppe, dppp; Z = C(O)OMe, C(O)OEt, C(O)NHPrn, NCO]. The single crystal structures of fac-Mn(CO)3(dppp)C(O)OEt and fac-Mn(CO)3(dppe)NCO

  摘要：

  The title compounds were prepared by the reaction of the cationic complex [M(CO)4(P-P)]+[BF4]- With the appropriate nucleophiles leading to fac-M(CO)3(P-P)Z [M = Mn, Re; P-P = dppe, dppp; Z = C(O)OMe, C(O)OEt, C(O)NHPrn, NCO] complexes. The X-ray structures of fac-Mn(CO)3(dppp)C(O)OEt and fac-Mn(CO)3(dppe)NCO are also reported.

  DOI：

  10.1016/s0277-5387(00)83162-9
• 作为产物：
  描述：

  fac-[bromo(1,2-bis(diphenylphosphino)ethane)tricarbonylmanganese(I)] 、 silver tetrafluoroborate 在 CO 作用下， 以 二氯甲烷 为溶剂， 以89-93的产率得到[Mn(CO)4(1,2-bis(diphenylphosphino)ethane)](BF4)
  参考文献：
  名称：

  The synthesis of alkoxycarbonyl, carbamoyl and isocyanato complexes, fac-M(CO)3(P-P)Z [M = Mn, Re; P-P = dppe, dppp; Z = C(O)OMe, C(O)OEt, C(O)NHPrn, NCO]. The single crystal structures of fac-Mn(CO)3(dppp)C(O)OEt and fac-Mn(CO)3(dppe)NCO

  摘要：

  The title compounds were prepared by the reaction of the cationic complex [M(CO)4(P-P)]+[BF4]- With the appropriate nucleophiles leading to fac-M(CO)3(P-P)Z [M = Mn, Re; P-P = dppe, dppp; Z = C(O)OMe, C(O)OEt, C(O)NHPrn, NCO] complexes. The X-ray structures of fac-Mn(CO)3(dppp)C(O)OEt and fac-Mn(CO)3(dppe)NCO are also reported.

  DOI：

  10.1016/s0277-5387(00)83162-9

文献信息

• A novel dimanganese complex linked by an unusually strong hydrogen bond. X-ray structure of the hydrogen-bonded complex and ab initio calculations
  作者：Thomas M Becker、Jeanette A.Krause Bauer、Janet E.Del Bene、Milton Orchin

  DOI：10.1016/s0022-328x(01)00829-4

  日期：2001.6

  3, are held together by an unusually strong O–H⋯F hydrogen bond (O⋯F=2.458(3) Å, H⋯F=1.52 Å) between the aqua ligand on one manganese and the fluoro atom on the other manganese. Using as a simple model the interaction between +Li(H2O) and FLi, the hydrogen bonding distance O–H⋯F was calculated to be; O⋯F=2.443 Å. Authentic 3 was prepared in a homogeneous system using CH2Cl2-soluble [Et4N]F.

  试图通过处理水络合物[（CO）3（dppe）Mn（OH 2）] BF 4（1）的CH 2 Cl 2溶液来制备氟络合物（CO）3（dppe）MnF（3）用NaF （aq）代替，我们分离出二锰配合物[（CO）3（dppe）Mn（OH 2）⋯FMn（dppe）（CO）3 ] BF 4（2）。两个部分1和3通过一个锰上的水配体与另一个锰上的氟原子之间的异常强的O–H⋯F氢键（O⋯F = 2.458（3）Å，H⋯F = 1.52Å）结合在一起。用一个简单的模型+ Li（H 2 O）和FLi之间的相互作用，计算出氢键距离O–H⋯F为：O⋯F ＝ 2.443埃。使用可溶于CH 2 Cl 2的[Et 4 N] F在均质系统中制备Authentic 3。
• Reaction of [fac-(CO)3(dppe)Mn(OH2)]BF4 with 13CO and conversion of the resulting tetracarbonyl to labeled isocyanato complexes
  作者：Thomas M. Becker、Koka Jayasimhulu、Milton Orchin

  DOI：10.1016/s0022-328x(00)00503-9

  日期：2000.9

  When 13CO is bubbled into a CH2Cl2 solution of [fac-(CO)3(dppe)Mn(OH2)]BF4 (dppe=Ph2PCH2CH2PPh2), the aqua ligand is replaced by the CO to give the tetracarbonyl, [(CO)3(13CO)(dppe)Mn]BF4 (1) in which the labeled CO appears exclusively at the site originally occupied by the aqua ligand. Treatment of this aqua complex with NaN3 leads to an approximate 50:50 mixture of isocyanates corresponding to attack

  当将13 CO鼓泡到[ fac-（CO）3（dppe）Mn（OH 2）] BF 4（dppe = Ph 2 PCH 2 CH 2 PPh 2）的CH 2 Cl 2溶液中时，aqua配体被取代生成四羰基[（CO）3（13 CO）（dppe）Mn] BF 4（1）的CO，其中标记的CO仅出现在最初由水配体占据的位点。用NaN 3处理这种水复合物导致大约50:50的异氰酸酯混合物对应于以相等的概率在标记的CO或其轴向配偶体处发生侵蚀。既不两个CO基团的反式在四羰基的P原子都受到影响。
• The preparation and reactions of the azides of fac-Mn(CO)3(P-P)N3. The X-ray crystal structures of fac-[Mn(CO)3(P-P)(OH2)]BF4, fac-Mn(CO)3(P-P)() [(P-P)=dppe and depe], and fac-[Mn(CO)3(depe)(PPh3)]BF4
  作者：Thomas M. Becker、Jeanette A. Krause-Bauer、Craig L. Homrighausen、Milton Orchin

  DOI：10.1016/s0277-5387(99)00161-8

  日期：1999.8

  A simple three-step, high-yield synthesis of the titled azides from Mn-2(CO)(10) and P-P is described involving the intermediate aqua complexes, fac-[Mn(CO)(3)(P-P)(H2O)]BF4, 3a,b. The aqua ligand is very labile; it is easily exchanged for D2O, PPh3, and NO2-. Crystal structures of the two titled aqua complexes and fac-[Mn(CO)(3)(depe)(PPh3)]BF4, 6a, are reported. The aqua complexes react instantaneously with aqueous NaN3 to give quantitative yields of the corresponding covalent azides which undergo the expected 1,3-dipolar additions with CF3CN to give the corresponding tetrazoles whose crystal structures are also reported. (C) 1999 Elsevier Science Ltd. All rights reserved.
• The synthesis and reactions of Mn and Re formyl complexes, fac-(PP)M(CO)3CHO. The X-ray structure of fac-(dppp)Mn(CO)3CH2OCH3
  作者：Santosh K. Mandal、Jeanette A. Krause、Milton Orchin

  DOI：10.1016/0022-328x(94)88015-8

  日期：1994.3

  Treatment of the salts fac-[(P-P)M(CO)4][BF4] (M = Mn, Re; P-P = dppe, dppp) with NaBH4 gives the corresponding formyl complexes, fac-(P-P)M(CO)3CHO in excellent yield. Solutions of these formyls undergo spontaneous loss of CO to give the corresponding hydrides, fac-(P-P)M(CO)3H. On treatment with methyl triflate or protic acids the formyls undergo expected disproportionation reactions; the X-ray crystal structure determination of one of the products, fac-(dppp)Mn(CO)3CH2OCH3, is reported.
• Mandal, Santosh K.; Ho, Douglas M.; Orchin, Milton, Inorganic Chemistry, 1991, vol. 30, # 9, p. 2244 - 2248
  作者：Mandal, Santosh K.、Ho, Douglas M.、Orchin, Milton

  DOI：——

  日期：——