| 1486466-34-5

• CAS: 1486466-34-5
• 化学式: C₃₅H₄₈CoN₂
• 分子量: 555.773
• InChiKey: PRYFGKWCLLACOZ-SCXLWNKFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [([(2,6-iPr2C6H3)NC(Me)]2)CoCl2] 、 甲苯 在 氢化钾 作用下， 反应 72.0h， 以54%的产率得到
  参考文献：
  名称：

  Synthesis and Characterization of Cobalt Complexes with Radical Anionic α-Diimine Ligands

  摘要：

  Three cobalt complexes, [LCo(mu-Cl)](2)center dot THF center dot Et2O (1), [LCo(eta(6)-toluene)] (2), and [LCo](2) (3), where L = [(2,6-iPr(2)C(6)H(3))NC(Me)](2), have been synthesized from reduction of the dichloro cobalt precursor [LCoCl2] by sodium or potassium metal. Single-crystal X-ray diffraction analyses reveal that the complexes display novel structures with the singly reduced form (L center dot-) of the a-diimine ligand: the dichloro-bridged binuclear complex 1, the mononuclear 2 with an eta(6)-coordinated toluene molecule, and the dimer 3 through Co-aryl interactions of two [LCo] units. The compounds were further characterized by EPR and magnetic studies.

  DOI：

  10.1021/om4003686