| 1323976-55-1

• CAS: 1323976-55-1
• 化学式: Cl₅HIrNO
• 分子量: 400.499
• InChiKey: IMRYSTOFTHVUQV-UHFFFAOYSA-I

反应信息

• 作为产物：
  描述：

  sodium tetrahydroborate 、 potassium pentachloronitrosyl iridate(III) 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  NO+, NO, NO−! Nitrosyl siblings from [IrCl5(NO)]−

  摘要：

  Pentachloronitrosyliridate(III) ([IrCl5(NO)] ), the most electrophilic NO+ known to date, can be reduced chemically and/or electrochemically by one or two electrons to produce the NO center dot and HNO/NO forms. The nitroxyl complex can be formed either by hydride attack to the NO+ in organic solvent, or by decomposition of iridium-coordinated nitrosothiols in aqueous solutions, while NO center dot is produced electrochemically or by reduction of [IrCl5(NO)] with H2O2. Both NO center dot and HNO/NO complexes are stable under certain conditions but tend to labilize the trans chloride and even the cis ones after long periods of time. As expected, the NO+ is practically linear, although the IrNO moiety is affected by the counterions due to dramatic changes in the solid state arrangement. The other two nitrosyl redox states comprise bent structures. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.02.063