Os2(CO)6(μ-γ-C5H3O2)(μ-PhCCHPh) | 669775-84-2

• 英文名称: Os2(CO)6(μ-γ-C5H3O2)(μ-PhCCHPh)
• CAS: 669775-84-2
• 化学式: C₂₅H₁₄O₈Os₂
• 分子量: 822.781
• InChiKey: VGPNLGXJHOSBQD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  Os3(CO)9(μ-H)(μ-γ-C5H3O2)(μ-PhCCHC6H4) 以 not given 为溶剂， 以0%的产率得到Os2(CO)6(μ-γ-C5H3O2)(μ-PhCCHPh)
  参考文献：
  名称：

  The photochemical and thermal reactions of a triosmium cluster carrying a γ-pyrone ligand with alkynes

  摘要：

  The reaction of the cluster Os-3(CO)(10)(mu-H)(mu-gamma-C5H3O2) (1) with a number of alkynes under thermal or visible light irradiation conditions, afforded in most cases the dinuclear complexes Os-2 (CO)(6)(mu-gamma-C5H3O2)(mu-LH) (L = PhCCPh, (BuCCH)-Bu-l, (BuCCMe)-Bu-l or EtCCEt) (2) or the trinuclear chain complexes Os-3(CO)(9)(mu-H)(mu-gamma-C5H3O2)(mu-RCCHC6H4) (R = H, Ph) (3). In the case of PhCCPh, a new isomer of Os-3(CO)(8)(PhCCPh)(2), viz., Os-3(CO)(8)(mu-PhCCPh)(mu-PhCCHC6H4) (7) has been isolated and characterised. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2003.09.022