| 866751-78-2

• CAS: 866751-78-2
• 化学式: Ag*BF₄*C₁₈H₁₀N₂O
• 分子量: 464.963
• InChiKey: AGIWUEWJUMANNS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,5-bis(4-ethynylphenyl)-[1,3,4]oxadiazole 、 silver tetrafluoroborate 以 二氯甲烷 、 苯 为溶剂， 以87%的产率得到
  参考文献：
  名称：

  Organometallic Coordination Polymers Generated from Bent Bis(acetylenylphenyl)oxadiazole Ligands and Ag(I) Salts

  摘要：

  Two new bent oxadiazole bridging benzoacetylene ligands 2,5-bis(4-ethynylphenyl)-1,3,4-oxadiazole (L9) and 2,5bis(3-ethynylphenyl)-1,3,4-oxadiazole (L10) were synthesized. The coordination chemistry of them with various inorganic Ag(I) salts has been investigated. Seven new coordination polymers were prepared by solution reactions and fully characterized by infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction. [Ag-2(L9)]-(SO3CF3)(2) (1) (triclinic, P (1) over bar; a = 10.292(4), b = 10.794(4), c = 11.399(5) angstrom; alpha = 98.894(5), beta = 102.360(6), gamma = 90.319(5)degrees; Z = 2), [Ag(L9)]SbF6 (2) (orthorhombic, Cmca; a = 19.059(9), b 12.922(6), c 15.609(7) angstrom; Z = 8), [Ag(L9)]BF4 (3) (orthorhombic, Cmca; a = 19.128(3), b 12.6042(18), c 28.003(4) angstrom; Z = 16), [Ag(L9)]CIO4 (4) (monoclinic, P2(1)/c; a = 8,5153(16), b = 19.722(4), c 10.320(2) angstrom; beta = 105.307(3)degrees; Z = 4), [Ag(L10)]-SO3CF3 (5) (triclinic, P (1) over bar; a = 9.0605(13), b = 10.4956(15), c = 10.8085(16) angstrom; alpha = 101.666(2), beta = 109,269(2), gamma = 100.944(2)0; Z = 2), [Ag(L10)(H2O)(0.5)]BF4-0.5H(2)O (6) (monoclinic, C2/m; a = 32.180(6), b = 17.027(3), c = 8.1453(15) angstrom; beta = 102.541(3)degrees; Z = 8), and {[Ag-2(L10)(2)(H2O)](CIO4)(2)}-o-xylene (7) (monoclinic, P2(1)/c; a = 8.1460(10), b = 17.326(2), c = 30.345(4) angstrom; beta = 97.71 degrees; Z = 4) were obtained by the combination of L9 and L10 with various Ag(I) salts in a benzene/methylene chloride mixed solvent system. In addition, the luminescent and electrical conductive properties of these new compounds were investigated.

  DOI：

  10.1021/ic0508223