[TBCorr]Al(py) | 1426913-17-8

• 英文名称: [TBCorr]Al(py)
• 英文别名: [5,10,15-tris(4-tert-butylphenyl)-2:3,7:8,12:13,17:18-tetrabenzo-2'',3'',7'',8'',12'',13'',17'',18''-octakis(carboxymethyl)corrolato]-aluminum(pyridine)
• CAS: 1426913-17-8
• 化学式: C₈₆H₇₆AlN₅O₁₆
• 分子量: 1462.55
• InChiKey: MMSPZUMJCSLVDY-VPGDKSHCSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  吡啶 、 5,10,15-tris(4-tert-butylphenyl)-2:3,7:8,12:13,17:18-tetrabenzo-2'',3'',7'',8'',12'',13'',17'',18''-octakis(carboxymethyl)corrole 、 三乙基铝 以 甲苯 、 水 为溶剂， 反应 0.17h， 以56%的产率得到[TBCorr]Al(py)
  参考文献：
  名称：

  Aluminum, Gallium, Germanium, Copper, and Phosphorus Complexes of meso-Triaryltetrabenzocorrole

  摘要：

  5,10,15-Triaryltetrabenzocorrole complexes of aluminum, gallium, germanium, and phosphorus were synthesized by coordination of these metal ions in the preformed triaryltetrabenzocorrole macrocycle, opening a way to the investigation of different metal complexes. The UV-vis spectra of these derivatives exhibit a red shift and broadening of all absorption bands because of the pi-extended aromatic system and distortion of the molecular framework. The electrochemical and photophysical behaviors of the free base and the metal complexes of meso-triaryltetrabenzocorrole were investigated and characterized.

  DOI：

  10.1021/ic400162y