(2-diphenylphosphinocyclopentene-1-(tert-butyl)imine)(allyl)palladium(II) chloride | 1014625-63-8

• 英文名称: (2-diphenylphosphinocyclopentene-1-(tert-butyl)imine)(allyl)palladium(II) chloride
• CAS: 1014625-63-8
• 化学式: C₂₅H₃₁ClNPPd
• 分子量: 518.375
• InChiKey: KEBRWXBUKPCXLL-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (2-diphenylphosphinocyclopentene-1-(tert-butyl)imine)(allyl)palladium(II) chloride 、 silver trifluoromethanesulfonate 以 二氯甲烷 为溶剂， 以89.7%的产率得到(2-diphenylphosphinocyclopentene-1-(tert-butyl)imine)(allyl)palladium(II) triflate
  参考文献：
  名称：

  Palladium(II) 3-Iminophosphine Complexes as Intermolecular Hydroamination Catalysts for the Formation of Imines and Enamines

  摘要：

  Palladium(II) 3-iminophosphine derivatives were screened as intermolecular hydroamination catalysts, with (3-iminophosphine)(allyl)palladium triflate determined to be the most active for the hydroamination of 1,3-cyclohexadiene and phenyl acetylene. The iminophosphine ligands were synthesized by a three-step process and coordinated in an eta(2) and eta(1) manner to palladium(II) chloride and (allyl)palladium(II) chloride, respectively.

  DOI：

  10.1021/om701106q
• 作为产物：
  描述：

  bis(η3-allyl-μ-chloropalladium(II)) 、 2-diphenylphosphinocyclopentene-1-(tert-butyl)imine 以 二氯甲烷 为溶剂， 以73.7%的产率得到(2-diphenylphosphinocyclopentene-1-(tert-butyl)imine)(allyl)palladium(II) chloride
  参考文献：
  名称：

  Palladium(II) 3-Iminophosphine Complexes as Intermolecular Hydroamination Catalysts for the Formation of Imines and Enamines

  摘要：

  Palladium(II) 3-iminophosphine derivatives were screened as intermolecular hydroamination catalysts, with (3-iminophosphine)(allyl)palladium triflate determined to be the most active for the hydroamination of 1,3-cyclohexadiene and phenyl acetylene. The iminophosphine ligands were synthesized by a three-step process and coordinated in an eta(2) and eta(1) manner to palladium(II) chloride and (allyl)palladium(II) chloride, respectively.

  DOI：

  10.1021/om701106q

文献信息

• Reactivity of (3-Iminophosphine)palladium(II) Complexes: Evidence of Hemilability
  作者：Andrew R. Shaffer、Joseph A. R. Schmidt

  DOI：10.1021/om900066t

  日期：2009.4.27

  Several palladium(II) 3-iminophosphine complexes were synthesized in moderate to high yield. With relevance to many palladium-catalyzed coupling reactions, these complexes incorporate a wide variety of ligands, including amines, alkyls, allyls, and triflates. The presence of both eta'- and eta(2)-coordination modes demonstrates the hemilability of the 3-iminophosphine ligand class, as determined by X-ray crystallography and NMR spectroscopy.