[Pt(2,2'-bipyridine)(2-((4,5-ethylenedithio)-1,3-dithiole-2-ylidene)-1,3-dithiole-4,5-dithionate(2-))][BF4] | 474510-59-3

• 英文名称: [Pt(2,2'-bipyridine)(2-((4,5-ethylenedithio)-1,3-dithiole-2-ylidene)-1,3-dithiole-4,5-dithionate(2-))][BF4]
• CAS: 474510-59-3
• 化学式: BF₄*C₁₈H₁₂N₂PtS₈
• 分子量: 794.719
• InChiKey: NDKRHUHQGZESSA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  Pt(2,2'-bipyridine)(2-((4,5-ethylenedithio)-1,3-dithiol-2-ylidene)-1,3-dithiol-4,5-dithionate(2-)) 、 N,N,N,N-tetraethylammonium tetrafluoroborate 以 二氯甲烷 为溶剂， 生成 [Pt(2,2'-bipyridine)(2-((4,5-ethylenedithio)-1,3-dithiole-2-ylidene)-1,3-dithiole-4,5-dithionate(2-))][BF4]
  参考文献：
  名称：

  X-ray crystal structure and electrical conductivity of [Pt(2,2′-bipyridine)(C8H4S8)][BF4] [C8H4S82−=2-{(4,5-ethylenedithio)-1,3-dithiole-2-ylidene}-1,3-dithiole-4,5-dithionate(2-)]

  摘要：

  [Pt(bpy)(C8H4S8)][BF4] (bpy = 2,2'-bipyridine: C8H4S82- = 2-{(4,5-ethylenedithio)-1,3-dithiole-2-ylidene}-1,3-dithiole-4,5-dithionate(2-)) was prepared by current-controlled electrolysis of a dichloromethane solution of [Pt(bpy)(C8H4S8)] with [NEt4][BF4] as an electrolyte. The X-ray crystal structure analysis revealed a columnar stacking of the one-electron oxidized, cationic moieties with some S-S non-bonded contacts (< 3.7 Angstrom) as well as an S-S layered interaction in another direction. The electrical conductivity measured for a compacted pellet was 5.0 x 10(-3) S cm(-1) at room temperature with activation energy of 0.05 eV. The energy band calculation of the oxidized species showed an essentially one-dimensional electron-conduction through the column. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)00844-7