bis[(Z)-6-((2-chlorobenzylamino)methylene)-2-methoxycyclohexa-2,4-dienone] manganese(II) chloride | 1401998-55-7

• 英文名称: bis[(Z)-6-((2-chlorobenzylamino)methylene)-2-methoxycyclohexa-2,4-dienone] manganese(II) chloride
• CAS: 1401998-55-7
• 化学式: C₃₀H₂₈Cl₄MnN₂O₄
• 分子量: 677.313
• InChiKey: KDYPRNCFUPPBQP-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  manganese(II) chloride tetrahydrate 、 2-chloro-[(2-hydroxybenzylidene)aminomethyl]phenol 以 甲醇 为溶剂， 以95%的产率得到bis[(Z)-6-((2-chlorobenzylamino)methylene)-2-methoxycyclohexa-2,4-dienone] manganese(II) chloride
  参考文献：
  名称：

  Spectroscopic Studies and Crystal Structure of Four-Coordinate Manganese(II) Chloride Complex

  摘要：

  High-spin new, manganese-(II) L2MnCl2, complex has been synthesized and its structure was elucidated by using elemental analysis, FT-IR, DTA-TG, H-1-NMR, C-13-NMR, and UV-Visible spectroscopic techniques. The structure of the compound has also been examined crystallographically. The title compound crystallizes in the triclinic space group P-1, with unit cell parameters: a = 11.354(1), b = 11.868(1), c = 12.080(1) angstrom, V = 1548.9(1) angstrom(3), D-x = 1.270 g.cm(-3), and Z = 2, respectively. The Mn atom was tetra-coordinated to form a distorted tetrahedral geometry by two oxygen atoms of L-2 and two chloride atoms of MnCl2 center dot 4H(2)O in the complex.

  DOI：

  10.1080/15533174.2011.618756