| 177986-11-7

• CAS: 177986-11-7
• 化学式: C₁₄H₁₈Cl₂O₁₂P₂Rh₂
• 分子量: 716.954
• InChiKey: KJQGFAFGMILMRG-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 碘 以 二氯甲烷 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Oxidative-addition reactions on planar chloranilate rhodium systems. Crystal structure of [Rh₂(µ-C₆Cl₂O₄)Me₂I₂(CO)₂(PPh₃)₂]

  摘要：

  The binuclear chloranilate complexes [Rh-2(mu-C6Cl2O4)L(4)] {L = CO 1 or CNR (R = toluene-p-sulfonyl-methyl) 2, L(4) = (CO)(2)(CNR)(2) 3, (CO)(2)(PPh(3))(2) 4 or (CO)(2)[P(OMe)(3)](2) 5} have been prepared and oxidative addition of the electrophiles Mel and I-2 investigated. Addition of XI (X = Me or I) to compounds 4 and 5, in a Rh:XI = 1:1 molar ratio, led to the symmetrical complexes [Rh-2(mu-C6Cl2O4)X(2)I(2)(CO2)(PR(3))(2)] (X = Me, R = Ph 6; X = I, R = Ph 7; X = I, R = OMe 8). Interaction of 4 and 5 with 1 mol of XI (X = Me or I) gave equimolecular mixtures of Rh-2(1) and Rh-2(III) systems. The crystal structure of 6 has been determined by X-ray diffraction methods.

  DOI：

  10.1039/dt9960002155
• 作为产物：
  描述：

  {Rh2(μ-chloranilate)(cycloocta-1,5-diene)2} 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Oxidative-addition reactions on planar chloranilate rhodium systems. Crystal structure of [Rh₂(µ-C₆Cl₂O₄)Me₂I₂(CO)₂(PPh₃)₂]

  摘要：

  The binuclear chloranilate complexes [Rh-2(mu-C6Cl2O4)L(4)] {L = CO 1 or CNR (R = toluene-p-sulfonyl-methyl) 2, L(4) = (CO)(2)(CNR)(2) 3, (CO)(2)(PPh(3))(2) 4 or (CO)(2)[P(OMe)(3)](2) 5} have been prepared and oxidative addition of the electrophiles Mel and I-2 investigated. Addition of XI (X = Me or I) to compounds 4 and 5, in a Rh:XI = 1:1 molar ratio, led to the symmetrical complexes [Rh-2(mu-C6Cl2O4)X(2)I(2)(CO2)(PR(3))(2)] (X = Me, R = Ph 6; X = I, R = Ph 7; X = I, R = OMe 8). Interaction of 4 and 5 with 1 mol of XI (X = Me or I) gave equimolecular mixtures of Rh-2(1) and Rh-2(III) systems. The crystal structure of 6 has been determined by X-ray diffraction methods.

  DOI：

  10.1039/dt9960002155