chloro(η5-dibenzo[c,g]fluorenide)bis(triphenylphosphyne)ruthenium | 1319717-65-1

• 英文名称: chloro(η5-dibenzo[c,g]fluorenide)bis(triphenylphosphyne)ruthenium
• CAS: 1319717-65-1
• 化学式: C₅₇H₄₃ClP₂Ru
• 分子量: 926.439
• InChiKey: HAZKCALSHOEWSV-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  chloro(η5-dibenzo[c,g]fluorenide)bis(triphenylphosphyne)ruthenium(II) toluene disolvate 以 二氯甲烷 为溶剂， 生成 chloro(η5-dibenzo[c,g]fluorenide)bis(triphenylphosphyne)ruthenium
  参考文献：
  名称：

  Dbf–ruthenocenes: Towards chiral halfsandwich Lewis acidic Dbf complexes

  摘要：

  In order to develop a new class of chiral metallocene catalysts, halfsandwich ruthenocenes of dibenzo[c,g]fluorenide (Dbf (1)) have been prepared. Structural and spectroscopic characterization of (eta(5)-Dbf)Ru(PPh3)(2)Cl and [(eta(5)-Dbf)Ru(PPh3)(2)(NCMe](+)[SbF6] provide evidence for strong metal-ligand binding in these sterically crowded complexes. In the solid state the complexes assume conformations ideal for transfer of the stereo information unto a prochiral substrate. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.03.038