[ReOCl2(N,N'-bis(2-pyridylmethyl)ethylenediamine)]Cl | 267221-53-4

• 英文名称: [ReOCl2(N,N'-bis(2-pyridylmethyl)ethylenediamine)]Cl
• 英文别名: [ReOCl2(H2pmen)]Cl
• CAS: 267221-53-4
• 化学式: C₁₄H₁₈Cl₂N₄ORe*Cl
• 分子量: 550.889
• InChiKey: DWEVRYUSWMCRRK-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [ReOCl2(N,N'-bis(2-pyridylmethyl)ethylenediamine)]Cl 、 水 在 air 作用下， 以 甲醇 、 水 为溶剂， 生成 [ReO2(N,N'-bis(2-pyridylmethyl)ethylenediamine)][ReO4]
  参考文献：
  名称：

  Chemistry of Re with N,N‘-Bis(2-pyridylmethyl)ethylenediamine (H₂pmen):  Hydrolysis, Dehydrogenation, and Ternary Complexes

  摘要：

  A number of Re complexes with N,N ' -bis(2-pyridylmethyl)ethylenediamine (H(2)pmen) have been made from [NH4]-[ReO4]. . [ReOCl(2)H(2)pmen)]Cl, [ReOCl(Hpmen)][ReO4], and [ReO2(H(2)pmen)] [ReO4] are related by hydrolysis/HCl substitution [ReOCl(Hpmen)] [ReO4] was structurally characterized and found to contain a water-stable amido-Re bend. Dehydrogenation of the N-donor ligand from each amine to imine with concomitant two-electron reduction of the Re center occurs readily in these systems. With suitable 3-hydroxy-4-pyrones, ternary complexes such as [(ReCl)-Cl-III(ma)(C14H14N4)][ReO4]. CH3OH, 5, were made from [NH4][ReO4], H(2)pmen . 4HCl and pyrones in one-pot syntheses. 5, a seven-coordinate Re-III complex, was structurally characterized.

  DOI：

  10.1021/ic0013025
• 作为产物：
  描述：

  ammonium perrhenate 、 N,N'-bis(2-pyridylmethyl)ethylenediamine*4HCl 在 PPh₃ 作用下， 以 甲醇 为溶剂， 生成 [ReOCl2(N,N'-bis(2-pyridylmethyl)ethylenediamine)]Cl
  参考文献：
  名称：

  Chemistry of Re with N,N‘-Bis(2-pyridylmethyl)ethylenediamine (H₂pmen):  Hydrolysis, Dehydrogenation, and Ternary Complexes

  摘要：

  A number of Re complexes with N,N ' -bis(2-pyridylmethyl)ethylenediamine (H(2)pmen) have been made from [NH4]-[ReO4]. . [ReOCl(2)H(2)pmen)]Cl, [ReOCl(Hpmen)][ReO4], and [ReO2(H(2)pmen)] [ReO4] are related by hydrolysis/HCl substitution [ReOCl(Hpmen)] [ReO4] was structurally characterized and found to contain a water-stable amido-Re bend. Dehydrogenation of the N-donor ligand from each amine to imine with concomitant two-electron reduction of the Re center occurs readily in these systems. With suitable 3-hydroxy-4-pyrones, ternary complexes such as [(ReCl)-Cl-III(ma)(C14H14N4)][ReO4]. CH3OH, 5, were made from [NH4][ReO4], H(2)pmen . 4HCl and pyrones in one-pot syntheses. 5, a seven-coordinate Re-III complex, was structurally characterized.

  DOI：

  10.1021/ic0013025