[Ru(2-(pyridin-2-yl)acridine(-1H))(2,2'-bipyridyl)2]PF6 | 1309783-76-3

• 英文名称: [Ru(2-(pyridin-2-yl)acridine(-1H))(2,2'-bipyridyl)2]PF6
• 英文别名: [Ru(pad)(bpy)2]PF6
• CAS: 1309783-76-3
• 化学式: C₃₈H₂₇N₆Ru*F₆P
• 分子量: 813.707
• InChiKey: GJMKVXYQWNMWGW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ru(2-(pyridin-2-yl)acridine(-1H))(2,2'-bipyridyl)2]PF6 以 not given 为溶剂， 生成 [Ru(2-(pyridin-2-yl)acridine)(2,2'-bipyridyl)2](2+)
  参考文献：
  名称：

  Proton-Induced Dynamic Equilibrium between Cyclometalated Ruthenium rNHC (Remote N-Heterocyclic Carbene) Tautomers with an NAD⁺/NADH Function

  摘要：

  Cyclometalated ruthenium(II) complexes having acridine moieties have been synthesized and characterized by spectroscopic methods. Protonation of the acridine nitrogen of the ruthenium(II) complexes not only causes dynamic equilibrium with remote N-heterocyclic carbene Ru=C complexes but also generates the NAD(+)-/NADH redox function driven by a proton-coupled two-electron transfer accompanying a reversible C-H bond formation in the pyridinium ring.

  DOI：

  10.1021/ic200315f
• 作为产物：
  描述：

  2,2'-联吡啶 、 [Ru(2-(pyridin-2-yl)acridine(-1H))(acetonitrile)4]PF6 以 乙二醇甲醚 为溶剂， 生成 [Ru(2-(pyridin-2-yl)acridine(-1H))(2,2'-bipyridyl)2]PF6
  参考文献：
  名称：

  Proton-Induced Dynamic Equilibrium between Cyclometalated Ruthenium rNHC (Remote N-Heterocyclic Carbene) Tautomers with an NAD⁺/NADH Function

  摘要：

  Cyclometalated ruthenium(II) complexes having acridine moieties have been synthesized and characterized by spectroscopic methods. Protonation of the acridine nitrogen of the ruthenium(II) complexes not only causes dynamic equilibrium with remote N-heterocyclic carbene Ru=C complexes but also generates the NAD(+)-/NADH redox function driven by a proton-coupled two-electron transfer accompanying a reversible C-H bond formation in the pyridinium ring.

  DOI：

  10.1021/ic200315f