azide | 33095-00-0

• 英文名称: azide
• 英文别名: azide-15N(1-)；Azanidylidene(azanidylidene)azanium
• CAS: 33095-00-0
• 化学式: N₃
• 分子量: 43.0134
• InChiKey: IVRMZWNICZWHMI-OUBTZVSYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  azide 、 [Fe(III)((CF3C6H4C3H2N2CH2C6H4CONHC6H4)(MeC3H2N2CONHC6H4)3C20H8N4)](triflate) 以 not given 为溶剂， 生成 [Fe(azide-15N)((F3CC6H4C3H2N2CH2C6H4CONHC6H4)(MeC3H2N2CONHC6H4)3C20H8N4))]
  参考文献：
  名称：

  Model Studies of Azide Binding to Functional Analogues of CcO

  摘要：

  N-3(-) binding to a functional model of CcO is investigated in its Fe3+, Fe3+Cu+, and Fe3+Cu2+ forms. A combination of EPR and FTIR indicates that N-3(-) binds in a bridging mode in the bimetallic sites and signature N-3(-) bands are identified for several forms of N-3(-) binding to the site. The presence of the distal metal increases the binding affinity of N-3(-). This bridging enables antiferromagnetic interaction between the two metal centers in the Fe3+Cu2+ state, which results in an EPR-silent ground state.

  DOI：

  10.1021/ic702294n